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Keywords:

  • asymmetric synthesis;
  • carbocycles;
  • cyclization;
  • heterocycles;
  • radicals
Thumbnail image of graphical abstract

Radically efficient: New and appealing enantioselective cyclizations leading to highly functionalized carbocycles and heterocycles have been reported (see scheme; TMS=trimethylsilyl). These methodologies, based on the cascade combination of radical and polar steps, provide alternatives to conventional methodologies.