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Keywords:

  • bond theory;
  • nitrenes;
  • phosphazenes;
  • reactive intermediates;
  • stabilization
Thumbnail image of graphical abstract

Finally isolated: The isolation of a nitridophosphane(V) was described for the first time by the research group of Bertrand. The reactivity and the possibility of stabilizing labile R2PN/R2NP species (see structure) are discussed.