Cover Picture: Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates) (Angew. Chem. Int. Ed. 49/2012)
Article first published online: 9 NOV 2012
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 51, Issue 49, page 12135, December 3, 2012
How to Cite
Berkessel, A., Elfert, S., Yatham, V. R., Neudörfl, J.-M., Schlörer, N. E. and Teles, J. H. (2012), Cover Picture: Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates) (Angew. Chem. Int. Ed. 49/2012). Angew. Chem. Int. Ed., 51: 12135. doi: 10.1002/anie.201208586
- Issue published online: 28 NOV 2012
- Article first published online: 9 NOV 2012
- Breslow intermediates;
- NMR spectroscopy;
- reaction mechanisms;
In their Communication on page 12194 ff., M. A. Petrukhina et al. describe pentadecker sandwich complexes with a Li–alkoxo core between corannulene bowls. These supramolecular aggregates may be useful for Li-ion-battery design.
A small-molecule inhibitor found to suppress the TLR1/TLR2-mediated inflammation response is presented by H. Yin et al. in their Communication on page 12246 ff. This compound is a valuable probe for these important signaling receptors.
In their Communication on page 12233 ff., P. Jonkheijm et al. describe a stable cucurbituril-mediated system for the preparation of noncovalent cell adhesive surfaces that can be electrochemically controlled.