This work is supported by the Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST) (D.J.).
Charge Dynamics in A Donor–Acceptor Covalent Organic Framework with Periodically Ordered Bicontinuous Heterojunctions†
Article first published online: 16 JAN 2013
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 52, Issue 7, pages 2017–2021, February 11, 2013
How to Cite
Jin, S., Ding, X., Feng, X., Supur, M., Furukawa, K., Takahashi, S., Addicoat, M., El-Khouly, M. E., Nakamura, T., Irle, S., Fukuzumi, S., Nagai, A. and Jiang, D. (2013), Charge Dynamics in A Donor–Acceptor Covalent Organic Framework with Periodically Ordered Bicontinuous Heterojunctions . Angew. Chem. Int. Ed., 52: 2017–2021. doi: 10.1002/anie.201209513
- Issue published online: 6 FEB 2013
- Article first published online: 16 JAN 2013
- Manuscript Received: 28 NOV 2012
- Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST)
- charge dynamics;
- electron transfer;
- organic frameworks
Light works: Mechanistic insights into the photochemical events and charge dynamics of a donor–acceptor covalent organic framework were given by time-resolved transient absorption spectroscopy and time-resolved electron spin resonance spectroscopy (see picture). The organic framework triggers ultrafast electron transfer and enables long-distance charge delocalization and exceptional long-term charge separation.