We thank “l’Agence Nationale de la Recherche” (ANR TECHBIOPHYP, ANR CATHYMETOXY) and the Labex project CHARMMMAT for financial support.
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Communication
Photoassisted Generation of a Dinuclear Iron(III) Peroxo Species and Oxygen-Atom Transfer†
Article first published online: 20 FEB 2013
DOI: 10.1002/anie.201210020
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Avenier, F., Herrero, C., Leibl, W., Desbois, A., Guillot, R., Mahy, J.-P. and Aukauloo, A. (2013), Photoassisted Generation of a Dinuclear Iron(III) Peroxo Species and Oxygen-Atom Transfer . Angew. Chem. Int. Ed., 52: 3634–3637. doi: 10.1002/anie.201210020
- †
Publication History
- Issue published online: 20 MAR 2013
- Article first published online: 20 FEB 2013
- Manuscript Received: 14 DEC 2012
- Manuscript Revised: 23 JAN 2012
Keywords:
- dioxygen activation;
- iron complexes;
- peroxo intermediates;
- photoreduction;
- ruthenium complexes
Closing the loop: Light absorption by a sensitizer–diiron(III) complex in the presence of a sacrificial electron donor and subsequent exposure to O2 led to the formation of the corresponding active diiron(III)–peroxo species, which can transfer an oxygen atom to a substrate (see scheme).