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Recyclable Mitsunobu Reagents: Catalytic Mitsunobu Reactions with an Iron Catalyst and Atmospheric Oxygen

Authors

  • Daisuke Hirose,

    1. School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)
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  • Dr. Tsuyoshi Taniguchi,

    Corresponding author
    1. School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)
    • School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)

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  • Prof. Dr. Hiroyuki Ishibashi

    1. School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)
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Errata

This article is corrected by:

  1. Errata: Corrigendum: Recyclable Mitsunobu Reagents: Catalytic Mitsunobu Reactions with an Iron Catalyst and Atmospheric Oxygen Volume 54, Issue 13, 3847, Article first published online: 16 March 2015

  • This research was supported by a Grant-in-Aid for Young Scientists (B) (23790008) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.

Abstract

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Aerobic recycling: A catalytic amount of a hydrazine reagent is sufficient to promote Mitsunobu reactions in the presence of triphenylphosphine, an iron catalyst, and air. The active form of the catalyst, an azo species, can be readily generated by iron-catalyzed aerobic oxidation. MS=molecular sieves, Pc=phthalocyanine.

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