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Keywords:

  • asymmetric catalysis;
  • natural products;
  • structure determination;
  • terpenoids;
  • total synthesis

While the two reported organometallic reactions (2[RIGHTWARDS ARROW]4 and 4[RIGHTWARDS ARROW]5) mediated by cage 1 are new, the overall reaction (2[RIGHTWARDS ARROW]5) in a common solvent has been reported by Knox and co-workers for R = Ph.14 Therefore, reference 14 is cited as an additional paper and the following sentence must be deleted from the introduction: “The overall reaction provides the first example of a photochemical organometallic transformation of a Ru2 dinuclear complex that occurs across the two metal centers.”