About phase: The coexistence of rhombohedral LiTMO2 (TM=Ni, Co, or Mn) and monoclinic Li2MnO3-like structures inside Li1.2Mn0.567Ni0.166Co0.067O2 is revealed directly at atomic resolution. The hetero-interface along the rh/mon zone axis direction is demonstrated, indicating the two-phase nature of these lithium-rich cathode materials (green Li, blue Mn, red O, cyan TM).
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