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Keywords:

  • amination;
  • cross-coupling;
  • N,P ligands;
  • palladium;
  • synthetic methods
Thumbnail image of graphical abstract

Mor(DalPhos) for Me(sylates): Described are the first examples of ketone mono-α-arylation and primary aliphatic amine monoarylation employing aryl methanesulfonate coupling partners. A range of functionalized aryl mesylates were employed with dialkyl ketones, and also with primary and secondary amines as well as the otherwise challenging coupling partners acetone and methylamine. Ad=adamantyl.