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Keywords:

  • amines;
  • aziridines;
  • copper;
  • multicomponent reactions;
  • trifluoromethylation
Thumbnail image of graphical abstract

A multitalented system: N-Migratory oxytrifluoromethylation and one-pot three-component reactions of allylamines as well as the aminotrifluoromethylation of alkenyl amines all proceeded efficiently in the presence of the Togni reagent (1) and CuI to afford a variety of β-trifluoromethylamine derivatives (see scheme).