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Keywords:

  • amines;
  • asymmetric catalysis;
  • imines;
  • organocatalysis;
  • synthetic methods
Thumbnail image of graphical abstract

Side by side: The title reaction is catalyzed by the chiral Brønsted acid (S)-1, and affords hitherto less accessible chiral propargylamines, having two adjacent stereocenters, in good to excellent diastereo- and enantioselectivities. Boc=tert-butoxycarbonyl.