Hungry hungry micropores: Reaction of [Zn4(μ3-OH)2(L)4(tBu)2] (LH=8-hydroxyquinoline) with CO2 forms a 3D microporous material with spherical zinc carbonate nanoclusters packed in a diamondoid manner in the solid state. This compound exhibits one of the highest Brunauer—Emmett—Teller surface areas for a noncovalent porous material, with high H2, CO2, and CH4 uptake.
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