3D Energetic Metal–Organic Frameworks: Synthesis and Properties of High Energy Materials


  • The authors gratefully acknowledge the support of the opening project of the State Key Laboratory of Science and Technology (Beijing Institute of Technology). The opening project number is ZDKT12-03.


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Energetic 3D MOFs: A structurally unique class of three-dimensional energetic metal–organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF shows the unprecedented heat of detonation of 3.62 kcal g−1.