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A Noble-Metal-Free Porous Coordination Framework with Exceptional Sensing Efficiency for Oxygen

Authors

  • Rui-Biao Lin,

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 (China)
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  • Fang Li,

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 (China)
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  • Si-Yang Liu,

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 (China)
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  • Xiao-Lin Qi,

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 (China)
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  • Prof. Dr. Jie-Peng Zhang,

    Corresponding author
    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 (China)
    • MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 (China)===

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  • Prof. Dr. Xiao-Ming Chen

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 (China)
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  • This work was supported by the “973 Project” (2012CB821706), NSFC (21225105, 21121061, and 21001120) and the innovative talents training funded projects for Ph.D. students of Sun Yat-Sen University.

Abstract

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Light material: By virtue of the unique framework structure and very high oxygen permeability, a noble-metal-free, highly fluorescent, porous coordination polymer demonstrates a rapid, reversible, efficient, stable, and selective fluorescence-quenching response toward oxygen.

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