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Keywords:

  • coordination polymers;
  • energetic materials;
  • heat of detonation;
  • metal–organic frameworks;
  • porous structures
Thumbnail image of graphical abstract

Energetic MOFs with 1D, 2D, or 3D structures were synthesized through a self-assembly strategy by using energetic organic linkers to bridge non-toxic metal ions. This new concept for energetic MOFs opens opportunities for developing new-generation primary explosives in the field of energetic materials.