Angewandte Chemie International Edition
Explore this journal >
Communication

Synthesis of Triangular Tripalladium Cations as Noble-Metal Analogues of the Cyclopropenyl Cation†

Authors

  • †

    We thank the UPMC, CNRS, IUF (L.F. and M.M.), and ANR (Grant Credox) for funding. We thank Prof. Pierre Gouzerh for discussions and Yanling Li for SQUID measurements.

Abstract

The first C3-symmetric 44-core-valence-electron triangular palladium clusters, [{(SAr′)(PAr3)Pd}3]+, have been synthesized by activation of the C[BOND]S bond of isothioureas. Owing to delocalized metal–metal bonding, these stable complexes are the first noble-metal analogues of the π-aromatic cyclopropenyl cation [C3H3]+, with their all-metal aromaticity involving d-type atomic orbitals.

Continue reading full article

Ancillary

Article Information

DOI

10.1002/anie.201310204

Format Available

Full text: HTML | PDF

Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Request Permissions

Keywords

  • aromaticity;
  • cluster compounds;
  • metal–metal interactions;
  • metallacycles;
  • palladium

Publication History

  • Issue online:
  • Version of record online:
  • Manuscript Received:

Funded by

  • UPMC
  • CNRS
  • IUF
  • ANR

Supporting Information

As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.

FilenameDescription
anie_201310204_sm_miscellaneous_information.pdf32666Kmiscellaneous_information

Please note: Wiley-Blackwell is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

Related content

Articles related to the one you are viewing

Citing Literature

  • Number of times cited: 18
  1. 1Cong-Qiao Xu, Deng-Hui Xing, Hai Xiao, Jun Li, Manipulating Stabilities and Catalytic Properties of Trinuclear Metal Clusters through Tuning the Chemical Bonding: H2 Adsorption and Activation, The Journal of Physical Chemistry C, 2017CrossRef
  2. 2Bernd Wrackmeyer, A Cyclotriborane Dianion and the Triboron Cation: “Light Ends” of the Hückel Rule, Angewandte Chemie International Edition, 2016, 55, 6, 1962Wiley Online Library
  3. 3Luis G. Perla, Slavi C. Sevov, A Stannyl-Decorated Zintl Ion [Ge18Pd3(SniPr3)6]2–: Twinned Icosahedron with a Common Pd3-Face or 18-VertexHypho-Deltahedron with a Pd3-Triangle Inside, Journal of the American Chemical Society, 2016, 138, 31, 9795CrossRef
  4. 4Alexander I. Boldyrev, Lai-Sheng Wang, Beyond organic chemistry: aromaticity in atomic clusters, Phys. Chem. Chem. Phys., 2016, 18, 17, 11589CrossRef
  5. 5Anna Monfredini, Veronica Santacroce, Pierre-Alexandre Deyris, Raimondo Maggi, Franca Bigi, Giovanni Maestri, Max Malacria, Boosting catalyst activity in cis-selective semi-reduction of internal alkynes by tailoring the assembly of all-metal aromatic tri-palladium complexes, Dalton Trans., 2016, 45, 40, 15786CrossRef
  6. 6Bernd Wrackmeyer, Ein Cyclotriboran-Dianion und das Tribor-Kation - “leichte Enden” der Hückel-Regel, Angewandte Chemie, 2016, 128, 6, 1998Wiley Online Library
  7. 7Ivan A. Popov, Fu-Xing Pan, Xue-Rui You, Lei-Jiao Li, Eduard Matito, Chao Liu, Hua-Jin Zhai, Zhong-Ming Sun, Alexander I. Boldyrev, Peculiar All-Metal σ-Aromaticity of the [Au2 Sb16 ]4− Anion in the Solid State, Angewandte Chemie, 2016, 128, 49, 15570Wiley Online Library
  8. 8Ivan A. Popov, Fu-Xing Pan, Xue-Rui You, Lei-Jiao Li, Eduard Matito, Chao Liu, Hua-Jin Zhai, Zhong-Ming Sun, Alexander I. Boldyrev, Peculiar All-Metal σ-Aromaticity of the [Au2 Sb16 ]4− Anion in the Solid State, Angewandte Chemie International Edition, 2016, 55, 49, 15344Wiley Online Library
  9. 9Yanlan Wang, Pierre-Alexandre Deyris, Tatiana Caneque, Florent Blanchard, Yanling Li, Franca Bigi, Raimondo Maggi, Sebastien Blanchard, Giovanni Maestri, Max Malacria, A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics, Chemistry - A European Journal, 2015, 21, 35, 12271Wiley Online Library
  10. 10Académie des Sciences Prizes: T. Loiseau, L. Fensterbank, A. Böckmann, J.-F. Carpentier / Arthur Birch Lectureship: S. Zard, Angewandte Chemie International Edition, 2015, 54, 15, 4427Wiley Online Library
  11. 11Pierre-Alexandre Deyris, Tatiana Cañeque, Yanlan Wang, Pascal Retailleau, Franca Bigi, Raimondo Maggi, Giovanni Maestri, Max Malacria, Catalytic Semireduction of Internal Alkynes with All-Metal Aromatic Complexes, ChemCatChem, 2015, 7, 20, 3266Wiley Online Library
  12. 12Kerstin Freitag, Christian Gemel, Paul Jerabek, Iris M. Oppel, Rüdiger W. Seidel, Gernot Frenking, Hung Banh, Katharina Dilchert, Roland A. Fischer, Die σ-aromatischen Cluster [Zn3]+und [Zn2Cu] - kleinste molekulare Bausteine für Messing, Angewandte Chemie, 2015, 127, 14, 4445Wiley Online Library
  13. 13Preise der Académie des Sciences: T. Loiseau, L. Fensterbank, A. Böckmann, J.-F. Carpentier / Arthur Birch Lectureship: S. Zard, Angewandte Chemie, 2015, 127, 15, 4503Wiley Online Library
  14. 14Kerstin Freitag, Christian Gemel, Paul Jerabek, Iris M. Oppel, Rüdiger W. Seidel, Gernot Frenking, Hung Banh, Katharina Dilchert, Roland A. Fischer, The σ-Aromatic Clusters [Zn3]+and [Zn2Cu]: Embryonic Brass, Angewandte Chemie International Edition, 2015, 54, 14, 4370Wiley Online Library
  15. 15Preise der Société Chimique de France 2014, Angewandte Chemie, 2014, 126, 50, 13872Wiley Online Library
  16. 16Société Chimique de France 2014 Prize Winners, Angewandte Chemie International Edition, 2014, 53, 50, 13654Wiley Online Library
  17. 17Alexander S. Ivanov, Ivan A. Popov, Alexander I. Boldyrev, Viktor V. Zhdankin, The I[DOUBLE BOND]X (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?, Angewandte Chemie, 2014, 126, 36, 9771Wiley Online Library
  18. 18Alexander S. Ivanov, Ivan A. Popov, Alexander I. Boldyrev, Viktor V. Zhdankin, The I[DOUBLE BOND]X (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?, Angewandte Chemie International Edition, 2014, 53, 36, 9617Wiley Online Library