Mesoporous Prussian Blue Analogues: Template-Free Synthesis and Sodium-Ion Battery Applications

Authors


  • This research was supported by the U.S. Department of Energy’s Office of Basic Energy Science, Division of Materials Sciences and Engineering, under contract with UT-Battelle, LLC.

Abstract

The synthesis of mesoporous Prussian blue analogues through a template-free methodology and the application of these mesoporous materials as high-performance cathode materials in sodium-ion batteries is presented. Crystalline mesostructures were produced through a synergistically coupled nanocrystal formation and aggregation mechanism. As cathodes for sodium-ion batteries, the Prussian blue analogues all show a reversible capacity of 65 mA h g−1 at low current rate and show excellent cycle stability. The reported method stands as an environmentally friendly and low-cost alternative to hard or soft templating for the fabrication of mesoporous materials.

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