We thank Dr. John Decatur and Dr. Yasuhiro Itagaki for NMR spectroscopic and mass spectrometric assistance, Alison Xiang Gao for the synthesis of some intermediates, and Marian Deuker for early studies. We also thank NSF (CHE-0619638) for an X-ray diffractometer and Prof. Gerard Parkin, Dr. Aaron Sattler, and Dr. Wesley Sattler for performing crystallographic analyses that aided our design. Financial support was provided by the National Institutes of Health (R01-GM84994), Bristol-Myers Squibb, Eli Lilly, Amgen, the NSF (Predoctoral Fellowship to N.E.W.), and the Research Corporation for Science Advancement (Cottrell Scholar Award to S.A.S.).
9-Membered Carbocycle Formation: Development of Distinct Friedel–Crafts Cyclizations and Application to a Scalable Total Synthesis of (±)-Caraphenol A†
Article first published online: 23 FEB 2014
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 53, Issue 13, pages 3409–3413, March 24, 2014
How to Cite
Wright, N. E. and Snyder, S. A. (2014), 9-Membered Carbocycle Formation: Development of Distinct Friedel–Crafts Cyclizations and Application to a Scalable Total Synthesis of (±)-Caraphenol A. Angew. Chem. Int. Ed., 53: 3409–3413. doi: 10.1002/anie.201311299
- Issue published online: 19 MAR 2014
- Article first published online: 23 FEB 2014
- Manuscript Received: 30 DEC 2013
- National Institutes of Health. Grant Number: R01-GM84994
- Bristol-Myers Squibb
- Eli Lilly
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