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Metastable Ionic Diodes Derived from an Amine-Based Polymer of Intrinsic Microporosity

Authors


  • E.M. and F.M. acknowledge financial support from the EPSRC (EP/K004956/1). Y.R. thanks the University of Bath for a fee waiver.

Abstract

A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger’s base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states.

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