A Stable Thiiranimine (pages 195–196)
Prof. Dr. Gerrit L'abbé, Jean-Paul Dekerk, Dr. Jean-Paul Declercq, Dr. Gabriel Germain and Prof. Dr. Maurice Van Meerssche
Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.197801951
The first thiiranimine has now been prepared by the route shown below. The bond lengths (in pm) are shown in the formula of the compound. The unusually long SC2 bond is opened on reaction of the three-membered ring.