Angewandte Chemie International Edition in English

Cover image for Vol. 25 Issue 10

October 1986

Volume 25, Issue 10

Pages 853–946

Currently known as: Angewandte Chemie International Edition

    1. Cover Picture (Angew. Chem. Int. Ed. Engl. 10/1986)

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198608531

      Thumbnail image of graphical abstract

      The cover shows a model for the structure of novel gold, rhodium, and ruthernium modifications: 13 metal atoms form a cluster; 13 clusters assemble to form the “supercluster” (M13)13; finally, n superclusters come together to form microcrystallites. These clusters were not discovered by chance, but in an investigation into the existence of small closed-shell clusters lacking protecting peripheral ligands. M55 clusters with ligands may be degraded electrochemically to naked M13 clusters; the species (M13)13 and [(M13)13]n were then identified by means of their Debye-Scherrer diffraction patterns. Further details are reported by G. Schmid et al. on p. 922.

    2. Graphical Abstract (Angew. Chem. Int. Ed. Engl. 10/1986)

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198608532

  1. Reviews

    1. Top of page
    2. Reviews
    3. Communications
    4. Book Reviews
    1. Computer Graphics in the Study of Metal Cluster Compounds (pages 853–860)

      Dr. Kim Henrick, Dr. Mary McPartlin and Miss Jill Morris

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198608533

      Seemingly real pictures of space-filling and ball-and-stick models can be generated in color on a computer display screen. This demonstration of the capability of modern computr programs, however, is not an end in itself: the kind and distribution of ligands on the surface of the central metal polyhedron determine many chemical properties of clusters. The models provide readily understandable information on unique features of the ligand arrangement and lead, in the case of clusters with interstitial H atoms, for example, to insights that are otherwise only obtained with considerable difficulty.

    2. High-Resolution Metal NMR Spectroscopy of Organometallic Compounds [New Analytical Methods (30)] (pages 861–881)

      Priv.-Doz. Dr. Reinhard Benn and Dr. Anna Rufińska

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198608611

      Recently developed techniques of NMR spectroscopy have allowed the investigation of metal nuclei having the nuclear spin quantum number 1/2 as well as of those with a nuclear quadrupole moment. The information available from the chemical shifts of selected metal nuclei (25Mg, 27Al, 49Ti, 57Fe, 59Co, 61Ni, 91Zr, 103Rh, and 195Pt) is especially well demonstrated for selected organometallic compounds. There exist relations between chemical shift and coordination number, oxidation states, and electron configuration of complex-bound metal atoms. The interpretation of the chemical shift of the metal nucleus in terms of frontier orbitals and thus in terms of the reactivity of the complexes is illustrated by several examples.

    3. Geometric and Topological Thinking in Organic Chemistry (pages 882–901)

      Prof. Nicholas J. Turro

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198608821

      The recognition of “sameness” within many families of structures and reactions is extremely important in learning organic chemistry. What ways of thinking have brought about the rapid conceptual and experimental advances in this field? “Geometric” and “topological” thinking have proved especially fruitful. Within the context of valid paradigms, these methods have allowed scientific problems to be defined and have assisted in the planning of experiments capable of their solution.

  2. Communications

    1. Top of page
    2. Reviews
    3. Communications
    4. Book Reviews
    1. The Structure of an Allenylsodium Derivative—Competition between Carbanion Resonance Delocalization and Gegenion Charge Localization (pages 902–903)

      Dipl.-Chem. Christian Schade, Prof. Dr. Paul von Ragué Schleyer, Prof. Dr. Erwin Weiss and Dipl.-Chem. Maren Geissler

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609021

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      The great importance of the counterion in determining the structure of a carbanion is clearly revealed by both calculations performed for allenyl anions and the results of the X-ray structure anlaysis of 1. Na favors the allenyl structure A having a strongly localized charge; the free anion and the lithium salts, on the other hand, are better described by the resonance structures A [LEFT RIGHT ARROW] B [LEFT RIGHT ARROW] C. The different behavior of organolithium and organosodium compounds is due to the stronger interaction of the anion with the smaller Li ion.

    2. Stepwise Addition of MeS to a Metal-Carbon Triple Bond—A New Type of Reaction in the Chemistry of Carbyne Complexes (page 904)

      Priv.-Doz. Dr. Fritz R. Kreissl and Dipl.-Chem. Hans Keller

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609041

      Thumbnail image of graphical abstract

      Succesive electrophilic attack on a carbyne and a carbene C atom charaterizes the title reaction, in which first the red, cationic complex 2 and then the yellow, doubly positive-charged complex 3 is formed from the carbynetungsten complex 1. This is the first example for electrophilic attack of a cation on the carbene C atom of a Fischer carbene complex.

    3. Isothermal Magnetic Phase Transitions Controlled by Reversible Electron/Ion Transfer Reactions (pages 905–906)

      Prof. Dr. Robert Schöllhorn and Dipl.-Chem. Andreas Payer

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609051

      The ferromagnetic copper chromoselenospinel CuCr2Se4 might serve as the basis for a chemically controlled magentic switch. In copper-containing electrolytes it can be transformed at 300 K into the cubic, nonstoichiometric phases Cu1 + yCr2Se4 (O ≤ y ≤ 1). At a critical value, yc, the system undergoes a ferromagnetic/paramagnetic phase transition. Since the uptake of copper is a reversible process, this chemical reaction can be used to change the magetic properties. Similar reactions have been observed for the ferromagentic phases CuCr2S4 and CuCr2Te4.

    4. Tricyclo[5.3.0.02,8]deca-3,5-dien-9-one and a New Route to C10H10 Isomers (pages 906–907)

      Prof. Dr. Rolf Gleiter, Dipl.-Chem. Horst Zimmermann and Dr. Wolfram Sander

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609061

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      A light-induced intramolecular [2 + 2] cycloaddition is the first step in the sequence of reactions that converts 1 into the tricyclic dienone 2. Compound 2 and its derivatives react both thermally and photochemically with bases. The new dihydroazulenes 3 and 4, among other products, are thereby obtained.

    5. Synthesis and Structure of [(C5Me5)2M2Se5]: Formation of a μ,η2-Tetraselenide Ligand at the M[BOND]M Double Bond of [(C5Me5)2M2(μ-CO)2)] (M [DOUBLE BOND] Co, Rh) (pages 907–908)

      Prof. Dr. Henri Brunner, Walter Meier, Dr. Joachim Wachter, Dr. Bernd Nuber and Prof. Dr. Manfred L. Ziegler

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609071

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      A planar selenium five-membered ring comprised of one Se2⊖ and one Semath image ligand bridging two metal atoms is present in 1. 1 and its cobalt analogue may be synthesized conveniently from [(C5Me5)2(CO)2M2] (M [DOUBLE BOND] Co, Rh) and gray selenium. Despite the diverse coordination behavior of polychalcogenides, such a structure was previously unknown.

    6. Carbonyl Olefinating Carbene-Tungsten Complexes and Their Suitability as Catalysts in Olefin-Metathesis (pages 909–910)

      Prof. Dr. Thomas Kauffmann, Renate Abeln, Dipl.-Chem. Siegfried Welke and Dorothea Wingbermühle

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609091

      Noteworthy properties as [DOUBLE BOND]CH2 transferring agents are exhibited by the tungsten complexes having the postulated structures 1 and 2, which are prepared in situ. They are the first tungsten complexes that are suitable for carbonylolefination (1 reacts with aldehydes and ketones, 2 preferentially with ketones); they are more stable than the known molybdenum complexes of this kind, and 2 can catalyze olefin metathesis. The solvent has a large effect on all of these reactions.

      • equation image
    7. Carbonyl Olefinating Aluminum-Molybdenum Complexes and an Analogous Tungsten Complex (pages 910–911)

      Prof. Dr. Thomas Kauffmann, Dipl.-Chem. Manfred Enk, Dipl.-Chem. Wilfried Kaschube, Dipl.-Chem. Euripides Toliopoulos and Dorothea Wingbermühle

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609101

      Thumbnail image of graphical abstract

      Modification of [DOUBLE BOND]CH2-transferring molybdenum and tungsten compounds with aluminum also affords carbonylolefination reagents. An example is the complex having the postulated bismethylene structure 1, prepared in situ. 1 is thermally labile. A main product of its decomposition, a yellow solid, was characterized.

    8. Carbene Complexes with Quinone Bisketal Functions (pages 911–913)

      Priv.-Doz. Dr. Karl Heinz Dötz, Michael Popall, Dr. Gerhard Müller and Dr. Klaus Ackermann

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609111

      Thumbnail image of graphical abstract

      The vinylogous-stabilized carbene complexes 2 (M [DOUBLE BOND] Cr, W) are formed by successive reaction of the naphthoquinone bisketal 1 with tBuLi, M(CO)6, and a trace of acid. In the case of the simpler 1,4-benzoquinone derivative, it is possible to prepare the carbene-chromium complex 3, which, as exprected, can undergo annelation with alkynes to form the B/C rings of anthracyclinones.

    9. Regioselective and Atropoisomeric-Selective Aryl Coupling to Give Naphthyl Isoquinoline Alkaloids: The First Total Synthesis of ([BOND])-Ancistrocladine (pages 913–915)

      Priv.-Doz. Dr. Gerhard Bringmann, Dipl.-Chem. Johannes R. Jansen and Heinz-Peter Rink

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609131

      Thumbnail image of graphical abstract

      The “most unusuall of all the isoquinoline alkaloids,” the title compound 2, is characterized by a biphenyl system configurationally stable to above 200°C. The key step in the synthesis is intramolecular C[BOND]C bond formation in the intermediate 1, in which the two molecular halves are joined by means of lactone formation.

    10. Cyclodisalazane Cations—Synthesis and Crystal Structure (pages 915–916)

      Prof. Dr. Ursula Kliebisch, Uwe Klingebiel, Dietmar Stalke and Prof. George M. Sheldrick

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609151

      Thumbnail image of graphical abstract

      Protonated nitrogen atoms in Si[BOND]N ring systems such as 1 are a novelty. The dication of 1 is formed by reaction of the unprotonated parent compound with Al2Cl6/CH2Cl2 (and a small amount of H2O). The counterion is also a novel dianion.

    11. A Salt of the Dication Cycloheptatrienylidenemethyleneditropylium (pages 916–917)

      Dipl.-Chem. Kiyoharu Mizumoto, Dipl.-Chem. Hideki Kawai, Dr. Keiji Okada and Prof. Dr. Masaji Oda

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609161

      Thumbnail image of graphical abstract

      The symmetrical di- and trications 1 and 2, respectively, containing tropylium moieties. were prepared from dicycloheptatrienyl-heptafulvalene. Reaction with Ph3CBF4 affords, via the (nonisolable) monocation, the dication 1, whose BF4 salt forms blue needles. 1 undergoes protonation by strong acids to give 2.

    12. Poly-Onio-Substituted Quinones as Strong Electron Acceptors (pages 917–919)

      Prof. Dr. Robert Weiss, Dipl.-Chem. Norbert J. Salomon, Dipl.-Chem. Georg E. Miess and Dipl.-Chem. Reinhard Roth

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609171

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      The bis- and tetrakispyridino-substituted quinones 1 and 2 are stronger oxidizing agents than the known neutral systems p-chloranil 3 and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ). The first reduction potential of 2 is + 0.73 V (vs. Ag/AgCl)! The new oxidizing agents 1 and 2 are also interesting preparatively, because they are readily obtainable from p-chloranil 3 and the transmaination reagent 4 and are insoluble in conventional aprotic solvents for all oxidation stages (which permits simple workup).

    13. Bis(pentamethylcyclopentadienyl)diphosphene—a Molecule with Fluxional Structure and Reactive P[BOND]C Bond (pages 919–921)

      Prof. Dr. Peter Jutzi, Dipl.-Chem. Udo Meyer, Prof. Dr. Bernt Krebs and Mechthild Dartmann

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609191

      What potential does the pentamethylcyclopentadienyl ligand Cp* have in diphosphene chemistry? An indication is provided by the synthesis of the crystalline diphosphene Cp*[BOND]P[DOUBLE BOND]P[BOND]Cp* from Cp*PCl2. The two Cp* ligands kinetically stabilize the P[DOUBLE BOND]P bond, resulting in a fluxional structure (degenerate [1,5]-sigmatropic rearrangements). They may be successively replaced by bulky amino or alkyl ligands.

    14. Dimeric 1,4-Dichloro-2,3,5,6-tetramethyl-1,4-dialumina-2,5-cyclohexadiene, a Compound with Aluminum-Olefin π-Bonds (pages 921–922)

      Priv.-Doz. Dr. Hansgeorg Schnöckel, Dipl.-Chem. Manfred Leimkühler, Dipl.-Chem. Rainer Lotz and Prof. Dr. Rainer Mattes

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609211

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      The low-temperature reaction of the “high-temperature” molecule AICI—the first preparative application of an Al subhalide—with CH3C[TRIPLE BOND]CCH3 gives the title compound 1. The monomers of this air- and moisture-sensitive compound are twisted by 90° with respect to each other. The dimer is held together by four Al-olefin π bonds. Such compounds were previously unknown.

    15. Novel Modifications of Gold, Rhodium, and Ruthenium—M13 Clusters as Building Blocks of “Superclusters” (pages 922–923)

      Prof. Dr. Günter Schmid and Dipl.-Chem. Norbert Klein

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609221

      Not alchemistry but rather chemistry is the basis for preparing a gold modification: [Au55(PPh3)12Cl6] can be degraded to naked Au13 clusters in CH2Cl2 solution by application of a 20-V d.c. potential, the outer layer of the cluster being lost. These smaller clusters reorganize, in turn, the form superclusters (Au13)13 and microcrystallites [(Au13)13]n, whose structure were determined by means of their X-ray powder data.

    16. Heterometallic Dinuclear Complexes by Ethene Displacement with Grignard Compounds or Diorganomagnesium Compounds (pages 923–925)

      Prof. Dr. Klaus Jonas, Dipl.-Chem. Gerd Koepe and Prof. Dr. Carl Krüger

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609231

      The incorporation of a complete Grignard compound into the coordination sphere of a transition-metal atom has been achieved for the first time by the reaction of 1, a well-known source of CpCo, with phenylmagnesium bromide in tetrahydrofuran (THF) in the presence of N,N,N′,N′-tetramethylethy-lenediamino (TMEDA). In the product 2, bonds exist between Co and Mg, Mg and Cphenyl, and Co and Cphenyl.

      • equation image
    17. First Dinuclear Complexes with Fourfold Alkyl-Bridging (pages 925–927)

      Prof. Dr. Klaus Jonas, Dipl.-Chem. Wolfgang Rüsseler, Prof. Dr. Carl Krüger and Dr. Eleonore Raabe

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609251

      Thumbnail image of graphical abstract

      The aesthetically pleasing V2 complex 2 exhibits very interesting bonding. 2 can be synthesized by reaction of cyclopentadienyl(η6-naphthalene)vanadium 1 with excess ethylene. Four fivefold coordinated, bridging C atoms and a small V-V distance (2.315(1) Å) characterize this novel organometallic compound.

    18. Benzene as Bridging Ligand in Main Group Metal-Transition Metal-Arene Complexes (pages 927–928)

      Prof. Dr. Klaus Jonas, Dipl.-Chem. Wolfgang Rüsseler, Dipl.-Chem. Klaus Angermund and Prof. Dr. Carl Krüger

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609271

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      A one-pot synthesis of benzene(cyclopentadienyl)vanadium 3 on a 10-g scale starts from vanadocene 1. Reaction with MeLi or nBuLi (R [DOUBLE BOND] Me, nBu) in the presence of 1,3-cyclohexadiene affords the LiV complex 2, the TMEDA analogue of which was used for a structure determination. Alcoholysis of 2 gives the paramagnetic complex 3.

    19. Synthesis of Diindenyldivanadium—a New Variant of the Reductive Degradation of Metallocenes and Related Compounds (pages 928–929)

      Prof. Dr. Klaus Jonas, Dipl.-Chem. Wolfgang Rüsseler, Prof. Dr. Carl Krüger and Dr. Eleonore Raabe

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609281

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      A V2 structural unit that is coordinated to all the C atoms of two sandwiching indenyl ligands characterizes the title compound 2. This dark violet, paramagentic sandwich complex can be synthesizd by reduction of diindenylvanadium 1 with potassium in tetrahydrofuran. The V-V distance in 2 is 2.351(1) Å.

    20. Formal Insertion of the HCO Fragment into a Trinuclear Cluster Metal-Carbyne Bond: Synthesis, Structure and Reactivity of Cluster-bound Ethynol (pages 929–931)

      Prof. Dr. K. Peter C. Vollhardt and Dr. Matthias Wolfgruber

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609291

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      The stable complex 2 (BFmath image salt) with HOC[TRIPLE BOND]CH as a ligand was prepared from the edge-protonated complex 1 and CO (55 bar) at room temperature. On silica gel, the HOC [TRIPLE BOND] CH ligand undergoes oxidation to give a [TRIPLE BOND]C[BOND]COOH ligand. When 2 is heated in the presence of CO, a rearrangement occurs, which formally involves a CO elimination (!) from the HOC[TRIPLE BOND]CH ligand.

    21. S4N4 as Tridentate Ligand in [IrX(CO)(PPh3)(S4N4)] Complexes (page 931)

      Dr. Frank Edelmann, Prof. Dr. Herbert W. Roesky, Dipl.-Chem. Claudia Spang, Dr. Mathias Noltemeyer and Prof. George M. Sheldrick

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609311

      Thumbnail image of graphical abstract

      An iridium-sulfur-nitrogen heterobicycle having a [4.3.0] framework is present in the air- and moisture-sensitive title compound 1. This surprising result was obtained by structure analysis of the long-known compound. The tridentate coordination of S4N4 to a transition-metal haldie is new; usually, the coordination occurs through a lone pair of electrons on a nitrogen atom. The bulky triphenylphosphane group is omitted in the picture on the right.

    22. Synthesis of the First Triphosphabutadiene (page 932)

      Prof. Dr. Rolf Appel, Bärbel Niemann, Winfried Schuhn and Dr. Falk Knoch

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609321

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      A new example for the replacement of carbon by phosphorus is provided by the red triphosphabutadiene 2. It has been prepared via two different routes: from the phosphapentadiene 1 by reaction with bases B and by condensation of a 1,3-diphosphapropene with a phosphane. In the crystal, 2 has cisoid double bonds (Aryl = 2,4,6-tri-tert-butylphenyl).

    23. A Self-Replicating Hexadeoxynucleotide (pages 932–935)

      Dr. Günter von Kiedrowski

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609322

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      Autocatalysis in a nonenzymatic, templete-directed condensation has been demonstrated in a system consisting of three oligonucleotides. A simple form of self-replication occurs, albeit only to a small extent: the template T organizes the building blocks Å and B in such a way that condensation can occur, leading to a second template molecule. Such a nonenzymatic process has long been sought, because it is postulated as a sine qua non for prebiotic evolution in theories on the origin of life.

    24. Asymmetric Elimination with High Induction: Synthesis of 1-Alkenylsulfoximides with Axial and Central Chirality (pages 935–937)

      Dipl.-Ing. Irene Erdelmeier, Prof. Dr. Hans-Joachim Gais and Prof. Dr. Hans J. Lindner

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609351

      Thumbnail image of graphical abstract

      The elimination of LiOSiMe3 in the title reaction (1 [RIGHTWARDS ARROW] 2) is accomplished in 91% yield and with ≥ 98% diastereoselectivity by reaction of 1 with nBuLi. Compound 1 is prepared by reaction of the corresponding ketone with LiCH2[BOND]S(O)(NMe)Ph. The elimination can be used, in the sense of an inverse Peterson reaction, for asymmetric carbonylolefination.

    25. Lithium-Coordinated α-Sulfonimidoyl Carbanions: Crystal Study of [(S)-(N-Methyl-S-phenylsulfonimidoyl)methyllithium]4. 2(tmeda) and Configurative Stability of [(N-Methyl-S-phenylsulfonimidoyl)isopropyllithium] (pages 938–939)

      Prof. Dr. Hans-Joachim Gais, Dipl.-Ing. Irene Erdelmeier, Prof. Dr. Hans J. Lindner and Dipl.-Ing. Jürgen Vollhardt

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609381

      Thumbnail image of graphical abstract

      The structure of lithioalkylsulfoximides of type 1, which are important in asymmetric synthesis, is full of surprises. In the crystal, the title compound (1a)4. 2(tmeda) contains two peripheral Li atoms with the expected coordination and two central Li atoms with three C and three N contacts. A barrier for rotation around the C[BOND]S bond has been measured for the second comound, 1b. The carbanions of 1 are not configurationally stable at the anionic C atoms.

    26. Solid-State and Solution Structure of α-(Phenylsulfonyl)allyllithium (pages 939–941)

      Prof. Dr. Hans-Joachim Gais, Dipl.-Ing. Jürgen Vollhardt and Prof. Dr. Hans J. Lindner

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609391

      Thumbnail image of graphical abstract

      Does the title compound prefer O[BOND]Li or C[BOND]Li contacts in the solid state? O[BOND]Li contacts are characteristic of lithiated phenylsulfones, C[BOND]Li contacts of allyllithium compounds. According to the X-ray structure analysis, the chiral dimer 1 with O[BOND]Li contacts is present in the crystal. The angle at C-1 corresponds to a middle position between sp3 and sp2 hybridization. These results also hold for the structure of 1 in solution.

    27. Nitromethane as d1,d1 Multiple Coupling Reagent for the Carbonyl Dianion Synthon. Practical Synthesis of Chalcogran (pages 941–942)

      Prof. Dr. Goffredo Rosini, Dr. Emanuela Marotta, Dr. Roberto Ballini and Dr. Marino Petrini

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609411

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      The spiroacetal group is a current synthetic goal, because it is present in many biologically active natural products. A four-step synthesis of chalcogran, 1, the main component of the aggregation pheromone of the bark beetle starts from nitromethane, 1-penten-3-one, and acrolein. This synthetic approach should allow the general synthesis of 1,6-dioxaspiro[4.4]nonane derivatives.

  3. Book Reviews

    1. Top of page
    2. Reviews
    3. Communications
    4. Book Reviews
    1. Book Review: The ACS Style Guide. Edited by J. S. Dodd (page 942)

      David I. Loewus

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609421

    2. Book Review: Organomercury Compounds in Organic Synthesis. By R. C. Larock (pages 943–944)

      Adalbert Maercker

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609432

    3. Book Review: Stereochemistry of Heterogeneous Metal Catalysis. By M. Bartók (page 944)

      Henri Brunner

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609441

    4. Book Review: The Structure of Volatile Sulphur Compounds. By I. Hargittai (page 946)

      Ralf Steudel

      Article first published online: 22 DEC 2003 | DOI: 10.1002/anie.198609461

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