A Triazadiphosphole (pages 7790–7793)
Sebastian Herler, Peter Mayer, Jörn Schmedt auf der Günne, Axel Schulz, Alexander Villinger and Jan J. Weigand
Article first published online: 31 OCT 2005 | DOI: 10.1002/anie.200502475
Two GaCl3adducts of 4-bis(trimethylsilyl)amino-1,2,4,3,5-triazadiphosphole were formed in simple high-yielding reactions. The adducts were fully characterized (see structure of the monoadduct) and shown to be stable at ambient temperature. The structure, bonding, and NMR spectra of the triazadiphosphole adducts are discussed on the basis of MO, NBO, and DFT calculations.