A High-Conductivity Crystal Containing a Copper(I) Coordination Polymer Bridged by the Organic Acceptor TANC (pages 5144–5147)
Makoto Tadokoro, Syuma Yasuzuka, Masaharu Nakamura, Takumi Shinoda, Toshinori Tatenuma, Minoru Mitsumi, Yoshiki Ozawa, Koshiro Toriumi, Harukazu Yoshino, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Takehiko Mori and Keizo Murata
Version of Record online: 6 JUL 2006 | DOI: 10.1002/anie.200600553
Molecular conductors: A new, modifiable electron acceptor with a 5,6,11,12-tetraazanaphthacene (TANC) framework was introduced in CuI–TANC coordination polymers (see picture). The conduction mechanism of a high-conductivity crystal constructed from these polymers can be described as 1D variable-range hopping based on the disordered F− ions.