Bridging the Gap between CO Adsorption Studies on Gold Model Surfaces and Supported Nanoparticles (pages 1981–1985)
Miguel López-Haro, Juan J. Delgado, José M. Cies, Eloy del Rio, Serafin Bernal, Robbie Burch, Miguel A. Cauqui, Susana Trasobares, José A. Pérez-Omil, Pascale Bayle-Guillemaud and José J. Calvino
Article first published online: 23 FEB 2010 | DOI: 10.1002/anie.200903403
A happy medium: Volumetric adsorption of carbon monoxide at 308 K and UHR-HAADF-STEM, HREM, and computer modeling techniques were compared. Experimental CO/Au ratios at saturation coverage for two supported gold catalysts were shown to fit very well the predictions of a nanostructural model that considers CO adsorption on gold sites with coordination numbers of less than eight.