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Materials, Nanoscience and Catalysis
Solvent-free reactions of alcohols with β-dicarbonyl compounds catalyzed by iron(III) chloride
Article first published online: 2 OCT 2007
DOI: 10.1002/aoc.1320
Copyright © 2007 John Wiley & Sons, Ltd.
1099-0739/asset/cover.gif?v=1&s=04bd9e08c0ca65d49547efbdbe335825939dd0de "Applied Organometallic Chemistry")
Additional Information
How to Cite
Yuan, Y., Shi, Z., Feng, X. and Liu, X. (2007), Solvent-free reactions of alcohols with β-dicarbonyl compounds catalyzed by iron(III) chloride. Applied Organometallic Chemistry, 21: 958–964. doi: 10.1002/aoc.1320
Publication History
- Issue published online: 11 OCT 2007
- Article first published online: 2 OCT 2007
- Manuscript Revised: 17 JUL 2007
- Manuscript Accepted: 17 JUL 2007
- Manuscript Received: 29 JUN 2007
Funded by
- Jiangsu Provincial Natural Science Foundation. Grant Number: BK2006549.
- Program for New Century Excellent Talents in Yangzhou University.
- Abstract
- References
- Cited By
Keywords:
- alcohols;
- green chemistry;
- iron;
- substitution
Graphical Abstract
The direct substitution of alcohols and β-dicarbonyl compounds was catalyzed with FeCl3 under solvent-free conditions. The catalyst loading could be decreased to 0.01 mol% in high activities.
Abstract
The direct substitution of alcohols and β-dicarbonyl compounds was catalyzed with FeCl3 under solvent-free conditions. The catalyst loading could be decreased to 0.01 mol% at high activities. It was shown that the reaction proceeded in two steps via the etherification of the alcohols. This method provided an easy and practical procedure for C![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
C bond formation.Copyright © 2007 John Wiley & Sons, Ltd.