Research Article

Silica-supported perchloric acid as a recyclable catalyst for efficient trimethylsilyl cyanide addition to aldehydes†

  1. Akbar Heydari*,
  2. Laila MáMani

Article first published online: 18 DEC 2007

DOI: 10.1002/aoc.1339

Issue

Applied Organometallic Chemistry

Applied Organometallic Chemistry

Volume 22, Issue 1, pages 12–14, January 2008

Additional Information

How to Cite

Heydari, A. and MáMani, L. (2008), Silica-supported perchloric acid as a recyclable catalyst for efficient trimethylsilyl cyanide addition to aldehydes. Applied Organometallic Chemistry, 22: 12–14. doi: 10.1002/aoc.1339

Author Information

  1. Chemistry Department, Tarbiat Modarres University, PO Box 14155-4838, Tehran, Iran

*Chemistry Department, Tarbiat Modarres University, PO Box 14155-4838, Tehran, Iran.

  1. †

    This paper dedicated to Mehdi Akbarzadeh for his contribution to the Iranian chemical industry.

Publication History

  1. Issue published online: 21 JAN 2008
  2. Article first published online: 18 DEC 2007
  3. Manuscript Revised: 18 SEP 2007
  4. Manuscript Accepted: 18 SEP 2007
  5. Manuscript Received: 2 SEP 2007

Funded by

  • National Research Council of Iran. Grant Number: 984

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Keywords:

  • silica-supported;
  • HClO4[BOND]SiO2;
  • trimethylsilyl cyanide;
  • Winkler reaction;
  • O-trimethylsilyl cyanohydrin

Graphical Abstract

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HClO4[BOND]SiO2 (0.6 mol%) acts as a highly effective catalyst for cyanation of various aldehydes to the corresponding O-trimethylsilyl cyanohydrins

Abstract

HClO4[BOND]SiO2 (0.6 mol%) acts as a highly effective catalyst for cyanation of various aldehydes to the corresponding O-trimethylsilyl cyanohydrins, in high yields and short reaction times. Copyright © 2007 John Wiley & Sons, Ltd.

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