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Keywords:

  • palladium;
  • arylboronates;
  • aryl halides;
  • borylation;
  • bis(pinacolato)diboron;
  • PEG 600

Abstract

A new protocol has been developed for the synthesis of arylboronates by a coupling reaction of aryl halides and bis(pinacolato)diboron using bis(triphenylphosphine)palladium dichloride/sodium acetate/polyethylene glycol 600 [Pd(PPh3)2Cl2/NaOAc/PEG 600] as an efficient catalytic system. Copyright © 2011 John Wiley & Sons, Ltd.