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Keywords:

  • silica support;
  • palladium nanoparticle;
  • biphenyls;
  • Suzuki–Miyaura reaction

Nanoparticles of palladium were supported on SiO2 by chemical vapor deposition technique. The obtained Pd nanocatalyst was characterized by various techniques. This catalyst was found to be very efficient for the selective cross-coupling of hydroxyl-substituted aryl iodides and bromide with arylboronic acids in water at room temperature to produce the corresponding hydroxyl-substituted biaryls. Coupling of phenylboronic acid with aryl iodides and bromides carrying substituents other than hydroxy group was also performed efficiently in refluxing ethanol. Copyright © 2012 John Wiley & Sons, Ltd.

Featured Compounds

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  1. 1 - 36
Compound 2a
Molecular Weight:220.0078
Molecular Formula:C6H5IO
InChIKey:VSMDINRNYYEDRN-UHFFFAOYSA-N
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Compound 2b
Molecular Weight:170.2072
Molecular Formula:C12H10O
InChIKey:YXVFYQXJAXKLAK-UHFFFAOYSA-N
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Compound 8a
Molecular Weight:202.005
Molecular Formula:C6H4BrNO2
InChIKey:ZDFBKZUDCQQKAC-UHFFFAOYSA-N
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Compound 8b
Molecular Weight:199.2054
Molecular Formula:C12H9NO2
InChIKey:BAJQRLZAPXASRD-UHFFFAOYSA-N
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Compound 1a
Molecular Weight:220.0078
Molecular Formula:C6H5IO
InChIKey:Not Available
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Compound 1b
Molecular Weight:170.2072
Molecular Formula:C12H10O
InChIKey:LLEMOWNGBBNAJR-UHFFFAOYSA-N
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Compound 3a
Molecular Weight:173.007
Molecular Formula:C6H5BrO
InChIKey:GZFGOTFRPZRKDS-UHFFFAOYSA-N
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Compound 3b
Molecular Weight:188.1977
Molecular Formula:C12H9FO
InChIKey:QSJNKJGPJVOGPK-UHFFFAOYSA-N
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Compound 4a
Molecular Weight:234.0344
Molecular Formula:C7H7IO
InChIKey:SYSZENVIJHPFNL-UHFFFAOYSA-N
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Compound 4b
Molecular Weight:184.2338
Molecular Formula:C13H12O
InChIKey:RHDYQUZYHZWTCI-UHFFFAOYSA-N
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Compound 5a
Molecular Weight:218.035
Molecular Formula:C7H7I
InChIKey:UDHAWRUAECEBHC-UHFFFAOYSA-N
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Compound 5b
Molecular Weight:168.2344
Molecular Formula:C13H12
InChIKey:ZZLCFHIKESPLTH-UHFFFAOYSA-N
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Compound 6a
Molecular Weight:187.034
Molecular Formula:C7H7BrO
InChIKey:QJPJQTDYNZXKQF-UHFFFAOYSA-N
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Compound 7a
Molecular Weight:171.034
Molecular Formula:C7H7Br
InChIKey:ZBTMRBYMKUEVEU-UHFFFAOYSA-N
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Compound 7b
Molecular Weight:186.2248
Molecular Formula:C13H11F
InChIKey:JSBJQQZPQJIGFJ-UHFFFAOYSA-N
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Compound 9a
Molecular Weight:182.017
Molecular Formula:C7H4BrN
InChIKey:HQSCPPCMBMFJJN-UHFFFAOYSA-N
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Compound 9b
Molecular Weight:179.2173
Molecular Formula:C13H9N
InChIKey:BPMBNLJJRKCCRT-UHFFFAOYSA-N
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Compound 10a
Molecular Weight:158.984
Molecular Formula:C4H3BrN2
InChIKey:GYCPLYCTMDTEPU-UHFFFAOYSA-N
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Compound 10b
Molecular Weight:156.1839
Molecular Formula:C10H8N2
InChIKey:LVXOXXGCJHYEOS-UHFFFAOYSA-N
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Compound 11a
Molecular Weight:191.453
Molecular Formula:C6H4BrCl
InChIKey:NHDODQWIKUYWMW-UHFFFAOYSA-N
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Compound 11b
Molecular Weight:188.653
Molecular Formula:C12H9Cl
InChIKey:FPWNLURCHDRMHC-UHFFFAOYSA-N
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Compound 12a
Molecular Weight:157.996
Molecular Formula:C5H4BrN
InChIKey:NYPYPOZNGOXYSU-UHFFFAOYSA-N
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Compound 12b
Molecular Weight:155.1959
Molecular Formula:C11H9N
InChIKey:HJKGBRPNSJADMB-UHFFFAOYSA-N
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Compound 13a
Molecular Weight:204.0084
Molecular Formula:C6H5I
InChIKey:SNHMUERNLJLMHN-UHFFFAOYSA-N
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Compound 13b
Molecular Weight:154.2078
Molecular Formula:C12H10
InChIKey:ZUOUZKKEUPVFJK-UHFFFAOYSA-N
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Compound 14a
Molecular Weight:249.0059
Molecular Formula:C6H4INO2
InChIKey:SCCCFNJTCDSLCY-UHFFFAOYSA-N
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Compound 15a
Molecular Weight:219.023
Molecular Formula:C6H6IN
InChIKey:Not Available
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Compound 15b
Molecular Weight:169.2224
Molecular Formula:C12H11N
InChIKey:DMVOXQPQNTYEKQ-UHFFFAOYSA-N
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Compound 16a
Molecular Weight:218.035
Molecular Formula:C7H7I
InChIKey:RINOYHWVBUKAQE-UHFFFAOYSA-N
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Compound 16b
Molecular Weight:168.2344
Molecular Formula:C13H12
InChIKey:ALLIZEAXNXSFGD-UHFFFAOYSA-N
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Compound 17a
Molecular Weight:254.0671
Molecular Formula:C10H7I
InChIKey:NHPPIJMARIVBGU-UHFFFAOYSA-N
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Compound 17b
Molecular Weight:204.2665
Molecular Formula:C16H12
InChIKey:IYDMICQAKLQHLA-UHFFFAOYSA-N
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Compound 18a
Molecular Weight:263.0325
Molecular Formula:C7H6INO2
InChIKey:ARJHCXYRCLMLQN-UHFFFAOYSA-N
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Compound 18b
Molecular Weight:213.2319
Molecular Formula:C13H11NO2
InChIKey:JRWXYDVBGGPNPY-UHFFFAOYSA-N
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Compound 19a
Molecular Weight:157.008
Molecular Formula:C6H5Br
InChIKey:QARVLSVVCXYDNA-UHFFFAOYSA-N
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Compound 20a
Molecular Weight:207.067
Molecular Formula:C10H7Br
InChIKey:DLKQHBOKULLWDQ-UHFFFAOYSA-N
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  1. 1 - 36