Applied Organometallic Chemistry

Cover image for Vol. 27 Issue 11

Special Issue: Organic/Inorganic Hybrid Materials

November 2013

Volume 27, Issue 11

Pages i–iii, 619–682

Issue edited by: Richard M. Laine

  1. Issue Information

    1. Top of page
    2. Issue Information
    3. Editorials
    4. Special Issue: Review
    5. Special Issue Articles
    1. Issue Information (pages i–iii)

      Article first published online: 31 OCT 2013 | DOI: 10.1002/aoc.3081

  2. Editorials

    1. Top of page
    2. Issue Information
    3. Editorials
    4. Special Issue: Review
    5. Special Issue Articles
    1. Preface for Hybrid Materials (page 619)

      Richard M. Laine

      Article first published online: 31 OCT 2013 | DOI: 10.1002/aoc.3082

  3. Special Issue: Review

    1. Top of page
    2. Issue Information
    3. Editorials
    4. Special Issue: Review
    5. Special Issue Articles
    1. Generation of structural diversity in polyphosphazenes (pages 620–629)

      Harry R. Allcock

      Article first published online: 16 JUL 2013 | DOI: 10.1002/aoc.2981

      Thumbnail image of graphical abstract

      Polyphosphazenes are hybrid inorganic-organic polymers with an enormous range of structures and properties. This diversity is achieved by use of an unusual macromolecular substitution protocol that allows almost infinite combinations of different organic side groups, and gives rise to property combinations that are difficult or impossible to generate in classical organic macromolecules. These properties are the reason for the growing interest in these polymers for diverse challenging applications.

  4. Special Issue Articles

    1. Top of page
    2. Issue Information
    3. Editorials
    4. Special Issue: Review
    5. Special Issue Articles
    1. Photoluminescence of as-synthesized and heat-treated phenyl-containing polysilylcarbodiimides: role of crosslinking and free carbon formation in polymer-derived ceramics (pages 630–638)

      Gabriela Mera, Ilaria Menapace, Scarlett Widgeon, Sabyasachi Sen and Ralf Riedel

      Article first published online: 7 JUN 2013 | DOI: 10.1002/aoc.2993

      Thumbnail image of graphical abstract

      Photoluminescence properties of carbon-rich polysilylcarbodiimides at room temperature and at annealing temperatures up to 500°C are discussed as function of crosslinking degree and formation of free carbon phase as PAHs.

    2. Room-temperature carbon–sulfur bond formation from Ni(II) σ-aryl complex via cleavage of the S–S bond of disulfide moieties (pages 639–643)

      Ken Okamoto, Jeremy B. Housekeeper and Christine K. Luscombe

      Article first published online: 27 MAY 2013 | DOI: 10.1002/aoc.2975

      Thumbnail image of graphical abstract

      The formation of ArSY (Y: C( = S)NMe2, Ph, P( = O)(OEt)2) by reductive elimination from σ-aryl complexes (M(PPh3)2PhBr, M = Ni, Pd) at ambient temperature, has been investigated, a result that shows an effective C−S cross-coupling reaction.

    3. Organosilicate polymer e-beam resists with high resolution, sensitivity and stability (pages 644–651)

      Sung-Il Lee, Jae Hwan Sim, Hae-Jeong Lee, Richard Kasica, Hyun-Mi Kim, Christopher L. Soles, Ki-Bum Kim and Do Y. Yoon

      Article first published online: 29 APR 2013 | DOI: 10.1002/aoc.2985

      Thumbnail image of graphical abstract

      An optimized terpolymer organosilicate resist prepared with p-chloromethylphenyl trimethoxysilane, norbornene ethyltrimethoxysilane, and tetraethoxysilane exhibits an excellent stability and allows the fabrication of 20-nm patterns with excellent line-edge roughness, with one quarter of the required dose for conventional HSQ resist.

    4. Cubic silsesquioxanes as tunable high-performance coating materials (pages 652–659)

      Hyun Wook Ro, Vera Popova, Dave J. Krug, Aaron M. Forster, Richard M. Laine and Christopher L. Soles

      Article first published online: 27 AUG 2013 | DOI: 10.1002/aoc.3032

      Thumbnail image of graphical abstract

      By systematically varying the length and nature of the organic tethers used to cross-link cubic silsesquioxanes into a covalent network, one can tune the performance of these materials as optical grade coatings. Schemes are presented to vary the mechanical modulus, coefficient of thermal expansion, surface energy and porosity in a systematic manner.

    5. Hybrid networks incorporating fluorous polyoxetane soft blocks (pages 660–665)

      Chenyu Wang, Wei Zhang and Kenneth J. Wynne

      Article first published online: 16 JUL 2013 | DOI: 10.1002/aoc.3022

      Thumbnail image of graphical abstract

      Force distance curve (adhesive failure) for removal of an epoxied aluminum cylinder from a representative 3F-UUrSil hybrid coating. Peak removal force is 0.26 MPa. Experiment carried out with a TA Instruments RSA III.

    6. Synthesis of acetoxyphenyl- and hydroxyphenyl-terminated polyfunctional T8, T10, T12 silsesquioxanes and initial studies on their use in the formation of highly crosslinked polyesters

      Jae Hwan Jung, Kathleen Chou, Joseph C. Furgal and Richard M. Laine

      Article first published online: 31 OCT 2013 | DOI: 10.1002/aoc.3054

      Thumbnail image of graphical abstract

      Synthesis of Acetoxy and Hydroxy Phenyl Terminated Polyfunctional T8, T10, T12 Silsesquioxanes and Initial Studies on Their Use in the Formation of Highly Crosslinked Polyesters.

    7. Epoxy-based hybrids using TiO2 nanoparticles prepared via a non-hydrolytic sol–gel route (pages 673–677)

      Manabu Kobayashi, Hitomi Saito, Bruno Boury, Kimihiro Matsukawa and Yoshiyuki Sugahara

      Article first published online: 24 SEP 2013 | DOI: 10.1002/aoc.3027

      Thumbnail image of graphical abstract

      TiO2 nanoparticles with an average diameter of less than 10 nm were prepared by a non-hydrolytic sol–gel route in a TiCl4-diisopropyl ether-CH2Cl2 system, and their surface was modified with n-octylphosphonic acid as shown by spectroscopic analyses. Highly transparent TiO2/epoxy hybrid films were prepared using the modified TiO2 nanoparticles. The refractive indices of TiO2/epoxy hybrid films at 633 nm increased monotonously from 1.51 for the pure polymer to 1.66 for the hybrid containing 62.4 mass% of TiO2 nanoparticles.

    8. Polyoctadecyl methacrylate brushes via surface-initiated atom transfer radical polymerization (pages 378–682)

      Heemin Yoo, Bo Yun Kim, Lawrence J. Hill, Jared J. Griebel, Woo Jin Chung and Jeffrey Pyun

      Article first published online: 30 MAY 2013 | DOI: 10.1002/aoc.2998

      Thumbnail image of graphical abstract

      The synthesis poly(octadecyl meth-acrylate)brushes on planar Si substrates using surface initiated atom transfer radical polymerization (SI-ATRP) is reported. We observed side chain crystallization of tethered PODMA chains resultng in the formation of lamellae morphologies with high aspect ratio nanofibers.

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