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Abstract

Synthesis of zirconium oligomeric polythioethers was effected using aqueous solution and interfacial techniques:

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The products are insoluble in all tried solvents and possess Zr[BOND]OH endgroups but no detectable quantities of R[BOND]SH, Zr[BOND]Cl, or Zr[BOND]N[BOND]Et-endgroups.