Thermal degradation of polymers. XI. Synthesis, polymerization, and thermal characterization of polymers of p-N,N-diethylaminostyrene in nitrogen
Article first published online: 9 MAR 2003
Copyright © 1976 John Wiley & Sons, Inc.
Journal of Applied Polymer Science
Volume 20, Issue 3, pages 639–649, March 1976
How to Cite
Oprea, S. and Still, R. H. (1976), Thermal degradation of polymers. XI. Synthesis, polymerization, and thermal characterization of polymers of p-N,N-diethylaminostyrene in nitrogen. J. Appl. Polym. Sci., 20: 639–649. doi: 10.1002/app.1976.070200307
- Issue published online: 9 MAR 2003
- Article first published online: 9 MAR 2003
- Manuscript Revised: 16 JUN 1975
- Manuscript Received: 30 MAY 1975
The monomer p-N,N-dimethylaminostyrene has been synthesized from p-N,N-diethylaniline and homopolymerized and copolymerized with styrene using 2,2′-azobisisobutyronitrile as free-radical initiator. The polymers have been characterized by thermal analysis (DTA, DSC, and TG). Glass transition temperatures have been measured and activation energies for degradation in nitrogen have been established by a variety of methods for comparative purposes.