Synthesis of organotin polymers from diallyl terephthalate and Bu3SnH
Article first published online: 10 MAR 2003
Copyright © 1990 John Wiley & Sons, Inc.
Journal of Applied Polymer Science
Volume 41, Issue 9-10, pages 2095–2101, 1990
How to Cite
Moriya, O. and Endo, T. (1990), Synthesis of organotin polymers from diallyl terephthalate and Bu3SnH. J. Appl. Polym. Sci., 41: 2095–2101. doi: 10.1002/app.1990.070410915
- Issue published online: 10 MAR 2003
- Article first published online: 10 MAR 2003
- Manuscript Accepted: 23 DEC 1989
- Manuscript Received: 4 AUG 1989
Crosslinked polymers containing both ester and organotin moieties were obtained in high yields from diallyl terephthalate (DATP) and tri-n-butyltin hydride via radical processes. The tributyltin ester (1) and the hydrostannated derivatives of DATP (2) were prepared and employed for copolymerizations with DATP. The copolymerizations of 1 and 2 proceeded effectively to afford the corresponding organotin polymers, in which the tributyltin group was incorporated through O–Sn and C–Sn bonds, respectively.