Surface modification of ultrahigh molecular weight polyethylene fibers by plasma treatment. II. Mechanism of surface modification

Authors

  • Shanglin Gao,

    Corresponding author
    1. Testing Centre, Chongqing Institute of Architecture and Engineering, 630045, People's Republic of China
    • Testing Centre, Chongqing Institute of Architecture and Engineering, 630045, People's Republic of China
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  • Yeguang Zeng

    1. Physics Department, Chongquing Teacher's College, 630047, People's Republic of China
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Abstract

A detailed examination has been undertaken of the influence of surface treatment on the adhesion of ultrahigh molecular weight polyethylene (UHMW-PE) fibers to epoxy resin. XPS, SEM, FTIR–ATR, LRS, and contact-angle measurements have been used to characterize the chemical and physical changes of the fibers. The results, taken together, suggest that the adhesion depends on three factors: (i) chemical bonding effects, after plasma treatment, with the introduction of various kinds of oxygen-containing groups into the surface of the nonpolar polyethylene, which greatly improve the surface energy of the fibers; (ii) mechanical keying effects; and (iii) the nonpolar dispersion force. It is concluded that these three factors can be regarded as additive and the contributions from each of them to fiber/resin adhesion are different and change with increasing treatment time. The optimum results are obtained when their respective contribution reaches about 60%, 30%, and 10%. © 1993 John Wiley & Sons, Inc.

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