Photoconductivity and photovoltaic effect of charge-transfer complex of poly[4-phenyl-2,6-(p-phenoxy) quinoline] and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone

Authors

  • Donghoon Choi,

    Corresponding author
    1. Polymer Chemistry Laboratory, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130–650, Korea
    • Polymer Chemistry Laboratory, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130–650, Korea
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  • Eun Ju Lee,

    1. Polymer Chemistry Laboratory, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130–650, Korea
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  • Kyeong-Ah Kim,

    1. Polymer Chemistry Laboratory, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130–650, Korea
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  • Soo Young Park,

    1. Polymer Chemistry Laboratory, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130–650, Korea
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  • Nakjoong Kim

    1. Polymer Chemistry Laboratory, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130–650, Korea
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Abstract

A new polymer containing a heterocyclic quinoline unit in the main chain, poly[4-phenyl-2,6-(p-phenoxy) quinoline] (PQ), was synthesized by an acid-catalyzed self-condensation reaction. We have found that PQ, which is generally a good insulator itself, can show photoconductivity when doped with an electron acceptor. From the UV-VIS absorption spectra, we found that PQ can form a charge-transfer (CT) complex with an electron acceptor, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ). The CT complex of the PQ-DDQ mixture showed distinct photoconductivity. Employing the DDQ composition ranging from 5 to 10 wt %, the ratio of dark and photoconductivity was calculated to be about 1 : 100 at an applied electric field of 105 V/cm. Additionally, the bilayer sample of PQ/DDQ exhibited a significant photovoltaic effect. The photovoltaic current increased with increasing photointensity. The open-circuit voltage was measured ranging from 0.4 to 0.7 V and the photovoltaic conversion efficiency was calculated to be 10−3−10−2%. The PQ film treated with DDQ vapor showed a relatively higher photovoltaic effect than that of the sample treated with DDQ solution. © 1993 John Wiley & Sons, Inc.

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