Thermal, mechanical, and surface characterization of starch–poly(vinyl alcohol) blends and borax-crosslinked films
Article first published online: 17 MAR 2005
Copyright © 2005 Wiley Periodicals, Inc.
Journal of Applied Polymer Science
Volume 96, Issue 4, pages 1313–1322, 15 May 2005
How to Cite
Sreedhar, B., Sairam, M., Chattopadhyay, D. K., Rathnam, P. A. S. and Rao, D. V. M. (2005), Thermal, mechanical, and surface characterization of starch–poly(vinyl alcohol) blends and borax-crosslinked films. J. Appl. Polym. Sci., 96: 1313–1322. doi: 10.1002/app.21439
- Issue published online: 17 MAR 2005
- Article first published online: 17 MAR 2005
- Manuscript Accepted: 10 OCT 2004
- Manuscript Received: 30 APR 2004
- mechanical properties;
- thermal properties.
Starch–poly(vinyl alcohol) (PVA) blends with different compositions were prepared and crosslinked with borax by in situ and posttreatment methods. Various amounts of glycerol and poly(ethylene glycol) with a molecular weight of 400 were added to the formulations as plasticizers. The pure starch–PVA blends and the crosslinked blends were subjected to differential scanning calorimetry, thermogravimetry, and X-ray photoelectron spectroscopic studies. Broido and Coats–Redfern equations were used to calculate the thermal decomposition kinetic parameters. The tensile strengths and elongation percentages of the films were also evaluated. The results suggested that the glass-transition temperature (Tg) and the melting temperature strongly depended on the plasticizer concentration. The enthalpy relaxation phenomenon was dependent on the starch content in the pure blend. The crosslinked films showed higher stability and lower Tg's than pure PVA and starch–PVA blends, respectively. High-resolution X-ray photoelectron spectroscopy provided a method of differentiating the presence of various carbons associated with different environments in the films. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1313–1322, 2005