Get access
Advertisement

Properties and degradation behavior of surface functionalized MWCNT/poly(L-lactide-co-ε-caprolactone) biodegradable nanocomposites

Authors

  • Maryam Amirian,

    1. School of Material Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang Province, People's Republic of China
    Search for more papers by this author
  • Jiehe Sui,

    Corresponding author
    1. School of Material Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang Province, People's Republic of China
    • School of Material Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang Province, People's Republic of China
    Search for more papers by this author
  • Ali Nabipour Chakoli,

    1. School of Material Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang Province, People's Republic of China
    Search for more papers by this author
  • Wei Cai

    1. School of Material Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang Province, People's Republic of China
    Search for more papers by this author

Abstract

In this research, poly(L-lactide-co-ε-caprolactone) (PLACL) reinforced with well-dispersed multiwalled carbon nanotubes (MWCNTs) nanocomposites were prepared by oxidization and functionalization of the MWCNT surfaces using oligomeric L-lactide (LA) and ε-caprolactone (CL). It is found that the surface functionalization can effectively improve the dispersion and adhesion of MWCNTs in PLACL. The surface functionalization will have a significant effect on the physical, thermomechanical, and degradation properties of MWCNT/PLACL composites. The tensile modulus, yield stress, tensile strength, and elongation at break of composite increased 49%, 60%, 70%, and 94%, respectively, when the concentration of functionalized MWCNTs in composite is 2 wt %. The in vitro degradation rate of nanocomposites in phosphate buffer solution increased about 100%. The glass transition temperature (Tg) of composites was decreased when the concentration of functionalized MWCNTs is 0.5 wt %. With further increasing the concentration of functionalized MWCNTs, the Tg was increased. The degradation kinetics of nanocomposites can be engineered and functionalized by varying the contents of pristine or functionalized MWCNTs. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

Get access to the full text of this article

Ancillary