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Molecularly imprinted “bulk” copolymers as selective sorbents for gallic acid

Authors

  • Tanta-Verona Nicolescu,

    1. Polymer Department, Research and Development National Institute of Chemistry and Petrochemistry ICECHIM-Bucharest, Romania
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  • Andrei Sarbu,

    Corresponding author
    1. Polymer Department, Research and Development National Institute of Chemistry and Petrochemistry ICECHIM-Bucharest, Romania
    • Polymer Department, Research and Development National Institute of Chemistry and Petrochemistry ICECHIM-Bucharest, Romania
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  • Stefan Ovidiu Dima,

    1. Polymer Department, Research and Development National Institute of Chemistry and Petrochemistry ICECHIM-Bucharest, Romania
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  • Cristian Nicolae,

    1. Polymer Department, Research and Development National Institute of Chemistry and Petrochemistry ICECHIM-Bucharest, Romania
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  • Dan Donescu

    1. Polymer Department, Research and Development National Institute of Chemistry and Petrochemistry ICECHIM-Bucharest, Romania
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Abstract

We report the synthesis of molecularly imprinted sorbents, selective for gallic acid. The particles were prepared by using acrylic acid, acrylonitrile, and hydroxyethyl methacrylate as functional monomers, whereas ethyleneglycol dimethacrylate and 1,4-buthanediol dimethacrylate were used as crosslinkers. Preparation and manipulation protocols were adjusted considering template's nature. To highlight the influence of monomer/crosslinker nature upon imprinted particles, the adsorption capacity, the imprinting factor, and the distribution and selectivity coefficients were calculated. An imprinting factor of 3.53 and a selectivity coefficient of 6.86 were found for hydroxyethyl methacrylate/ethylene glycol methacrylate system. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci. 2013

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