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Shape memory properties of polycaprolactone-based polyurethanes prepared by reactive extrusion

Authors

  • Shengguang Weng,

    1. Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, People's Republic of China
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  • Zhean Xia,

    1. Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, People's Republic of China
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  • Jianding Chen,

    Corresponding author
    1. Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, People's Republic of China
    • Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, People's Republic of China
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  • Luanluan Gong

    1. Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, People's Republic of China
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Abstract

The shape memory properties of polycaprolactone-based polyurethanes (PCLUs) synthesized via a novel route of reactive extrusion were investigated in terms of the deformation amplitude, temperature, and rate by differential scanning calorimetry (DSC), dynamic mechanical analyzer, and polarized optical microscopy (POM). DSC analysis shows that the crystalline melting temperature and crystallinity of PCLU increased monotonically with increasing the average polymerization degree equation image of poly(ε-caprolactone) (PCL) block. The retract force increased with increasing the temperature and reached the maximum (6–7 MPa) within 45–55°C. Furthermore, a modified model with two recovery stages was postulated to elucidate the shape memory process, which is visually presented by POM analysis. The two stages of tensile and compressive recovery are distinguished by the inflexion temperature, within 43–48°C and 64–66°C, respectively. The shape fixity is about 60–70% and can be improved to 100% by choosing proper deformation temperature. The tensile deformation recovery ratio was 80–98% due to the water absorption, whereas the compressive deformation recovery ratio was almost 100%. Besides, recovery tests show that the lowest recovery temperature ranged from 24 to 47°C was influenced by the deformation temperature, rate and the PCL block equation image. Thus, the shape memory properties can be adjusted according to different purposes. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

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