Nitroanilines enhancing the holographic data storage characteristics of the 9,10-phenanthrenequinone-doped poly(methyl methacrylate) photopolymer

Authors

  • Cheng-Jung Ko,

    1. Department of Materials Science and Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
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  • Yi-Nan Hsiao,

    Corresponding author
    1. Department of Photonics and Institute of Electro-Optical Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
    • Department of Photonics and Institute of Electro-Optical Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
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  • Shiuan-Huei Lin,

    1. Department of Electrophysics, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
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  • Po-Lin Chen,

    1. Department of Photonics and Institute of Electro-Optical Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
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  • Wha-Tzong Whang,

    Corresponding author
    1. Department of Materials Science and Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
    • Department of Materials Science and Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
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  • Ken Y. Hsu,

    1. Department of Photonics and Institute of Electro-Optical Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
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  • Yu-Sheng Hsiao,

    1. Department of Materials Science and Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
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  • Chun-Chao Chen

    1. Department of Materials Science and Engineering, National Chiao Tung University, Hsin-Chu 300, Taiwan, Republic of China
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Abstract

This article describes an approach toward improving the characteristics of a photopolymer for holographic data storage application. The maximum diffraction efficiency (ηmax) and dynamic range (M#) of 9,10-phenanthrenequinone (PQ)-doped poly(methyl methacrylate; PMMA) both improved significantly after co-doping with one of three nitroanilines—N,N-dimethyl-4-nitroaniline (DMNA), N-methyl-4-nitroaniline (MNA), and 4-nitroaniline (pNA). In particular, the value of ηmax increased from 38% for the PMMA/PQ system to 72% for the PMMA/PQ/DMNA system (a 1.89-fold improvement) and the value of M# increased accordingly from 2.7 to 7.3 (a 2.70-fold improvement). Thus, the holographic data storage characteristics of PMMA/PQ photopolymers can be improved through co-doping with nitroaniline compounds. We also investigated the mechanism of the nitroaniline-induced improvement in optical storage performance using proton nuclear magnetic resonance and X-ray photoelectron spectroscopy. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

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