Transparent, superhydrophobic, and colored silicone–carbon composite coatings were prepared by oxidative chemical vapor deposition (oCVD) of bulk silicone at ambient pressure. The colors, wettability, morphologies, and transparency of the coatings can be easily varied via changing both the concentration of gaseous oxygen and the deposition temperature. Typically, the black, brown, and yellow silicone–carbon composite coatings with different superhydrophobicity and transparency were achieved under oxygen-deficient atmospheres. Furthermore, the colored samples showed photoluminescence when they were excited by ultraviolet (UV) light, which is due to the fluorescence of carbons embedded inside the as-prepared coatings. In addition, more regular papillae and nanofibers with excellent superhydrophobicity were obtained at higher deposition temperatures. Our method was believed to develop a new strategy for fabricating multifunctional silicone–carbon composite coatings. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40400.