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Keywords:

  • allylic compounds;
  • heck reaction;
  • palladium;
  • regioselectivity;
  • silver
Thumbnail image of graphical abstract

A highly selective Fujiwara–Moritani oxidative Heck reaction of allyl esters with unreactive arenes via C[BOND]H bond activation was developed, in which β-H elimination is highly chemo-, regio- and stereoselective. Moreover, even electron-deficient arenes are tolerated in this type of C[BOND]H activation.

Featured Compounds

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  1. 1 - 38
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2a
Molecular Weight:100.1158
Molecular Formula:C5H8O2
InChIKey:FWZUNOYOVVKUNF-UHFFFAOYSA-N
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 1a
Molecular Weight:78.1118
Molecular Formula:C6H6
InChIKey:UHOVQNZJYSORNB-UHFFFAOYSA-N
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Compound 3a
Molecular Weight:176.2118
Molecular Formula:C11H12O2
InChIKey:Not Available
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Compound 1b
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:YXFVVABEGXRONW-UHFFFAOYSA-N
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Compound 1c
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:RDOXTESZEPMUJZ-UHFFFAOYSA-N
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Compound 1d
Molecular Weight:112.557
Molecular Formula:C6H5Cl
InChIKey:MVPPADPHJFYWMZ-UHFFFAOYSA-N
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Compound 1e
Molecular Weight:136.1479
Molecular Formula:C8H8O2
InChIKey:QPJVMBTYPHYUOC-UHFFFAOYSA-N
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Compound 1f
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:KWOLFJPFCHCOCG-UHFFFAOYSA-N
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Compound 1g
Molecular Weight:123.1094
Molecular Formula:C6H5NO2
InChIKey:LQNUZADURLCDLV-UHFFFAOYSA-N
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Compound 1h
Molecular Weight:146.1098
Molecular Formula:C7H5F3
InChIKey:GETTZEONDQJALK-UHFFFAOYSA-N
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Compound 1i
Molecular Weight:106.165
Molecular Formula:C8H10
InChIKey:URLKBWYHVLBVBO-UHFFFAOYSA-N
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Compound 1j
Molecular Weight:122.1644
Molecular Formula:C8H10O
InChIKey:CHLICZRVGGXEOD-UHFFFAOYSA-N
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Compound 1k
Molecular Weight:142.583
Molecular Formula:C7H7ClO
InChIKey:YRGAYAGBVIXNAQ-UHFFFAOYSA-N
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Compound 3b
Molecular Weight:190.2384
Molecular Formula:C12H14O2
InChIKey:DAFYRFPANVKQOF-ONEGZZNKSA-N
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Compound 3c
Molecular Weight:206.2378
Molecular Formula:C12H14O3
InChIKey:XQNPFRPIWBMLRN-ONEGZZNKSA-N
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Compound 3d
Molecular Weight:210.657
Molecular Formula:C11H11ClO2
InChIKey:HINLSDCWYUURAI-HWKANZROSA-N
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Compound 3e
Molecular Weight:234.2479
Molecular Formula:C13H14O4
InChIKey:LXPJMRWUHKLCFI-GQCTYLIASA-N
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Compound 3f
Molecular Weight:218.2485
Molecular Formula:C13H14O3
InChIKey:XKKZEXWHECZYFU-GQCTYLIASA-N
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Compound 3g
Molecular Weight:221.2093
Molecular Formula:C11H11NO4
InChIKey:NPKDFEUSBFLEME-HWKANZROSA-N
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Compound 3h
Molecular Weight:244.2097
Molecular Formula:C12H11F3O2
InChIKey:IGAGKUSWVRBAAJ-HWKANZROSA-N
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Compound 3i
Molecular Weight:204.2649
Molecular Formula:C13H16O2
InChIKey:ZKSOFISCNASFFC-SNAWJCMRSA-N
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Compound 3ja
Molecular Weight:220.2643
Molecular Formula:C13H16O3
InChIKey:VNDUTCHSSZJKFA-SNAWJCMRSA-N
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Compound 3jb
Molecular Weight:220.2643
Molecular Formula:C13H16O3
InChIKey:UALOIZVLBHZGDQ-SNAWJCMRSA-N
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Compound 3ka
Molecular Weight:240.683
Molecular Formula:C12H13ClO3
InChIKey:SLWWXYFGVUEQKS-ONEGZZNKSA-N
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Compound 3kb
Molecular Weight:240.683
Molecular Formula:C12H13ClO3
InChIKey:CYXOTPJXKVNOES-ONEGZZNKSA-N
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2e
Molecular Weight:116.1152
Molecular Formula:C5H8O3
InChIKey:YHLVIDQQTOMBGN-UHFFFAOYSA-N
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Compound 1l
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:HUMNYLRZRPPJDN-UHFFFAOYSA-N
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Compound 2b
Molecular Weight:114.1424
Molecular Formula:C6H10O2
InChIKey:LYWCPTCPTWCZSZ-UHFFFAOYSA-N
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Compound 2d
Molecular Weight:170.2487
Molecular Formula:C10H18O2
InChIKey:DOJDQRFOTHOBEK-UHFFFAOYSA-N
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Compound 2f
Molecular Weight:176.2118
Molecular Formula:C11H12O2
InChIKey:FXTGIMSXGTUMAN-UHFFFAOYSA-N
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Compound 3l
Molecular Weight:190.2384
Molecular Formula:C12H14O2
InChIKey:DSWDNUYFUXOVBI-CMDGGOBGSA-N
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Compound 3m
Molecular Weight:204.2649
Molecular Formula:C13H16O2
InChIKey:IZHDTKCQQSJEGY-MDZDMXLPSA-N
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Compound 3n
Molecular Weight:246.3447
Molecular Formula:C16H22O2
InChIKey:PHOQNPPEIYLGSI-OUKQBFOZSA-N
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Compound 3o
Molecular Weight:192.2112
Molecular Formula:C11H12O3
InChIKey:NXPVXGMVVNYCGZ-VMPITWQZSA-N
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Compound 3p
Molecular Weight:280.3178
Molecular Formula:C18H16O3
InChIKey:GIADJKMVZMRYEU-WQRHYEAKSA-N
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  1. 1 - 38