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Keywords:

  • click chemistry;
  • cycloaddition;
  • mechanical bond;
  • supramolecular chemistry;
  • thiol additions

Abstract

Supramolecular chemistry and mechanostereochemistry have been major beneficiaries of the concepts and reactions pioneered under the “click chemistry” philosophy. The success of the copper(I) 1,3-dipolar cycloaddition between azides and alkynes, resulting in the triazole ring has inspired the application of other emerging click reactions, for example, Diels–Alder cycloadditions, thiol–ene/yne chemistry, and nitrile N-oxide cycloadditions, towards the creation of advanced functional supramolecular and mechanostereochemical systems. In this Focus Review, recent advances in the use of click chemistry in these fields are highlighted.

Featured Compounds

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  1. 1 - 29
Compound 1
Molecular Weight:1812.4463
Molecular Formula:C120H142N6O9
InChIKey:XVKDXQQAMKTMIK-UHFFFAOYSA-N
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Compound 1+
Molecular Weight:1812.4463
Molecular Formula:C120H142N6O9
InChIKey:XVKDXQQAMKTMIK-UHFFFAOYSA-N
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Compound 1.Cl[BOND]
Molecular Weight:1847.899
Molecular Formula:C120H143ClN6O9
InChIKey:WEILPXDVLLDAKM-UHFFFAOYSA-M
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Compound 2
Molecular Weight:797.0069
Molecular Formula:C48H52N12
InChIKey:AEKANQJBOUNVQE-UHFFFAOYSA-N
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2.Cl[BOND]
Molecular Weight:832.46
Molecular Formula:C48H53ClN12
InChIKey:QVUGYHMYHGSHOD-UHFFFAOYSA-M
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Compound 4
Molecular Weight:325.4114
Molecular Formula:C17H23N7
InChIKey:GAIOUKHWOJVARF-UHFFFAOYSA-N
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Compound 4a
Molecular Weight:393.4439
Molecular Formula:C23H19N7
InChIKey:NSJFFRPMIQCQHC-UHFFFAOYSA-N
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Compound 4b4+
Molecular Weight:1786.62
Molecular Formula:C92H76N28Pd2
InChIKey:JSNWNMDDRGZQPR-UHFFFAOYSA-N
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Compound 5
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6+
Molecular Weight:593.336
Molecular Formula:C27H25Br2N6
InChIKey:PQYFMHZPCGNRIC-UHFFFAOYSA-N
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Compound 7(2+)
Molecular Weight:422.5248
Molecular Formula:C26H26N6
InChIKey:RDUOISCPZXTHAI-UHFFFAOYSA-N
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Compound 8(2+)
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8(4+)
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10(6+)
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9(2+)
Molecular Weight:2691.2776
Molecular Formula:C162H188N10O26
InChIKey:XHVPTDMJEXYRBH-UHFFFAOYSA-N
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Compound 9(4+)
Molecular Weight:2691.2776
Molecular Formula:C162H188N10O26
InChIKey:XHVPTDMJEXYRBH-UHFFFAOYSA-N
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Compound 10(4+)
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 11
Molecular Weight:2912.554
Molecular Formula:C180H194N12O10S3Zn2
InChIKey:MWZQNCLZXHXOSK-VWUYFVMXSA-L
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Compound 12
Molecular Weight:3569.132
Molecular Formula:C240H194N12O8S2Zn2
InChIKey:HPTPJRQJWFNHNH-VWUYFVMXSA-L
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Compound 13+
Molecular Weight:899.076
Molecular Formula:C50H59NO12S
InChIKey:RVFWZQHEKHJRDN-UHFFFAOYSA-O
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Compound 14+
Molecular Weight:1557.67
Molecular Formula:C110H61NO10
InChIKey:QGLINUZXBOPGGM-UHFFFAOYSA-O
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Compound 13a+
Molecular Weight:835.0121
Molecular Formula:C50H59NO10
InChIKey:PZFLILGNYFHDMQ-UHFFFAOYSA-O
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Compound 15
Molecular Weight:933.2246
Molecular Formula:C56H76N4O8
InChIKey:AYLQCLWSJSARHQ-SDYRXFTASA-N
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Compound 16+
Molecular Weight:510.6037
Molecular Formula:C24H39N5O7
InChIKey:DSODLWPBULUBAG-UHFFFAOYSA-O
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Compound 17+
Molecular Weight:1079.3091
Molecular Formula:C72H63N5O5
InChIKey:PFRIGRLICSEIQR-UHFFFAOYSA-O
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Compound 19+
Molecular Weight:1814.305
Molecular Formula:C113H121NO16S2
InChIKey:BESHRYVMHZGROI-UHFFFAOYSA-O
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Compound 20+
Molecular Weight:2032.767
Molecular Formula:C128H159NO16S2
InChIKey:UXAYNZYMQOSALX-UHFFFAOYSA-O
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Compound 21+
Molecular Weight:908.0628
Molecular Formula:C52H62N2O12
InChIKey:SZRCOCPDWYDHME-UHFFFAOYSA-O
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  1. 1 - 29