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Keywords:

  • arylboronic acid;
  • gold;
  • homocoupling;
  • matrix effect;
  • polymers
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Polyhydroxy biopolymers play dual roles in the stabilization of gold clusters as well as the activation of arylboronic acids through reversible binding. In acidic pH (4.57), the electronic state of boron is changed into that observed at pH 9 in the vicinity of Au/chit or Au/starch, which favors the transmetalation process; this change is why homocoupling product was observed even in acidic solutions.

Featured Compounds

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  1. 1 - 4
Compound A
Molecular Weight:121.93
Molecular Formula:C6H7BO2
InChIKey:HXITXNWTGFUOAU-UHFFFAOYSA-N
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Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2
Molecular Weight:154.2078
Molecular Formula:C12H10
InChIKey:ZUOUZKKEUPVFJK-UHFFFAOYSA-N
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Compound 3
Molecular Weight:94.1112
Molecular Formula:C6H6O
InChIKey:ISWSIDIOOBJBQZ-UHFFFAOYSA-N
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