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Keywords:

  • click chemistry;
  • copper;
  • ferrocene;
  • platinum;
  • rotaxanes

Abstract

Two ferrocenylmethyl ammonium salts were used as axle components of pseudorotaxanes with dibenzo[24]crown-8. The pseudorotaxane with an alkyne terminal group in the axle component underwent a Cu-catalyzed Huisgen coupling reaction (click reaction) with an alkyl azide to afford cationic [2]rotaxanes with a triazole group in the axle molecule. The rotaxane reacted with Ac2O to produce neutral rotaxanes with an amide group in the axle component. Both cationic and neutral rotaxanes were treated with K[PtCl3(CH2[DOUBLE BOND]CH2)] to form the PtII-containing rotaxanes.

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Featured Compounds

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  1. 1 - 7
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound [1a]PF6
Molecular Weight:481.193
Molecular Formula:C19H22F6FeNOP
InChIKey:XGWGJUJHJGHVBE-UHFFFAOYSA-O
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Compound [1b]PF6
Molecular Weight:547.294
Molecular Formula:C24H28F6FeNOP
InChIKey:BOAOHNVQPLHQKQ-UHFFFAOYSA-O
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound [2a]PF6
Molecular Weight:929.699
Molecular Formula:C43H54F6FeNO9P
InChIKey:INPMVZGZPBBNIV-UHFFFAOYSA-O
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Compound [2b]PF6
Molecular Weight:995.8
Molecular Formula:C48H60F6FeNO9P
InChIKey:WWAVWLOHAAYGCJ-UHFFFAOYSA-O
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Compound 4
Molecular Weight:1127.147
Molecular Formula:C62H78FeN4O12
InChIKey:PCURQTJNTUNTOB-UHFFFAOYSA-N
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