Communication

Grafting of Metallacarboranes onto Self-Assembled Monolayers Deposited on Silicon Wafers

  1. Dr. Emilio José Juárez-Pérez1,
  2. Dr. Michel Granier2,
  3. Prof. Clara Viñas1,
  4. Dr. P. Hubert Mutin2,
  5. Dr. Rosario Núñez1,*

Article first published online: 30 NOV 2011

DOI: 10.1002/asia.201100750

Issue

Chemistry – An Asian Journal

Chemistry – An Asian Journal

Volume 7, Issue 2, pages 277–281, February 6, 2012

Additional Information

How to Cite

Juárez-Pérez, E. J., Granier, M., Viñas, C., Mutin, P. H. and Núñez, R. (2012), Grafting of Metallacarboranes onto Self-Assembled Monolayers Deposited on Silicon Wafers. Chem. Asian J., 7: 277–281. doi: 10.1002/asia.201100750

Author Information

  1. 1

    Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus U.A.B. 08193 Bellaterra (Spain), Fax: (+34) 93-580-5729

  2. 2

    Institut Charles Gerhardt Montpellier, UMR5253 CNRS-UM2-ENSCM-UM1, Université de Montpellier 2, Place Eugène Bataillon, F-34095 Montpellier Cedex 5 (France)

*Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus U.A.B. 08193 Bellaterra (Spain), Fax: (+34) 93-580-5729

Publication History

  1. Issue published online: 1 FEB 2012
  2. Article first published online: 30 NOV 2011
  3. Manuscript Received: 5 SEP 2011

Funded by

  • MICINN. Grant Number: CTQ2010-16237
  • Generalitat de Catalunya. Grant Number: 2009/SGR/00279
  • CNRS
  • French Ministry of Research

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article (HTML) Get PDF (487K)

Keywords:

  • cluster compounds;
  • metallacarboranes;
  • self-assembly;
  • silicon oxide modification;
  • surface chemistry
Thumbnail image of graphical abstract

Stuck on you: Amine-, oxyamine-, and isocyanate-terminated self-assembled monolayers were deposited on silicon wafers for reaction with cobaltabisdicarbollide derivatives. The reaction of the isocyanate group with [NMe4][8-NH2-C4H8O2-3,3-Co(1,2-C2B9H10)(1,2-C2B9H11)] gave homogeneous monolayers of cobaltabisdicarbollide moieties covalently linked to the surface (see picture).

Featured Compounds

Compound 1
Molecular Weight:456.654
Molecular Formula:C4H22B18CoCs
InChIKey:VDOMMQCFQVCYQU-UHFFFAOYSA-N
View compound in article | Full details | Search this compound
Compound 2
Molecular Weight:410.846
Molecular Formula:C8H29B18CoO2
InChIKey:KEIWPWDPTCVEQD-UHFFFAOYSA-N
View compound in article | Full details | Search this compound
Compound 3
Molecular Weight:501.013
Molecular Formula:C12H43B18CoN2O2
InChIKey:FPUWAINIZXUXSF-UHFFFAOYSA-N
View compound in article | Full details | Search this compound
View Full Article (HTML) Get PDF (487K)