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Stepwise Construction of a AgI9–CuII4 Heterometallic Cluster Incorporating Two Unusual Vertex-Shared Trigonal-Bipyramidal Silver Polyhedra

Authors

  • Dr. Di Sun,

    Corresponding author
    1. Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100 (China), Fax: (+86) 531-88364218
    • Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100 (China), Fax: (+86) 531-88364218

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  • Liangliang Zhang,

    1. Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100 (China), Fax: (+86) 531-88364218
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  • Zhihao Yan,

    1. Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100 (China), Fax: (+86) 531-88364218
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  • Prof. Daofeng Sun

    Corresponding author
    1. Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100 (China), Fax: (+86) 531-88364218
    • Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100 (China), Fax: (+86) 531-88364218

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Abstract

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One step at a time: A novel tridecanuclear AgI9–CuII4 heterometallic cluster comprising four [Cu(phen)2]2+ units on the periphery and one interior [Ag9(mna)8]7− cluster was synthesized in a stepwise manner and characterized. The interior [Ag9(mna)8]7− cluster contains two unusual vertex-shared trigonal-bipyramidal silver polyhedra.

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