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Keywords:

  • alcohols;
  • copper;
  • ethers;
  • H-phosphonates;
  • α-hydroxy phosphonates
Thumbnail image of graphical abstract

Easy PC: α-Hydroxy phosphonates were synthesized by copper/tert-butyl hydroperoxide (TBHP)-catalyzed oxidative addition reactions of H-phosphonates with alcohols or ethers. Diverse α-hydroxy phosphonates were obtained from substituted benzyl alcohols or alkyl alcohols and alkyl ethers in moderate to good yields.

Featured Compounds

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  1. 1 - 36
Compound 1a
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:WVDDGKGOMKODPV-UHFFFAOYSA-N
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Compound 2a
Molecular Weight:166.1553
Molecular Formula:C6H15O3P
InChIKey:BLKXLEPPVDUHBY-UHFFFAOYSA-N
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Compound 3a
Molecular Weight:272.2772
Molecular Formula:C13H21O4P
InChIKey:QCHMUMZWEDNROG-UHFFFAOYSA-N
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Compound 3i
Molecular Weight:302.3032
Molecular Formula:C14H23O5P
InChIKey:DIRMEVNJPBGTAP-UHFFFAOYSA-N
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Compound 3j
Molecular Weight:286.3038
Molecular Formula:C14H23O4P
InChIKey:NLBYWECTKOSQHZ-UHFFFAOYSA-N
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Compound 3k
Molecular Weight:317.2748
Molecular Formula:C13H20NO6P
InChIKey:LPFODHLIMXAGEN-UHFFFAOYSA-N
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Compound 3l
Molecular Weight:344.3399
Molecular Formula:C16H25O6P
InChIKey:HWXRFRRBXUZUEZ-UHFFFAOYSA-N
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Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3c
Molecular Weight:351.173
Molecular Formula:C13H20BrO4P
InChIKey:MLXVDCPAXSYNHY-UHFFFAOYSA-N
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Compound 3e
Molecular Weight:351.173
Molecular Formula:C13H20BrO4P
InChIKey:YLNYYEKPUCIHTA-UHFFFAOYSA-N
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Compound 3g
Molecular Weight:306.722
Molecular Formula:C13H20ClO4P
InChIKey:HHXAPODRXNWZLQ-UHFFFAOYSA-N
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Compound 2b
Molecular Weight:138.1021
Molecular Formula:C4H11O3P
InChIKey:MJUJXFBTEFXVKU-UHFFFAOYSA-N
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Compound 3d
Molecular Weight:323.12
Molecular Formula:C11H16BrO4P
InChIKey:VNBHBEOSJRDJJB-UHFFFAOYSA-N
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Compound 3f
Molecular Weight:323.12
Molecular Formula:C11H16BrO4P
InChIKey:OFZFDAPSYVGZIG-UHFFFAOYSA-N
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Compound 3h
Molecular Weight:278.669
Molecular Formula:C11H16ClO4P
InChIKey:RIQJHXWKWXDLFM-UHFFFAOYSA-N
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3b
Molecular Weight:298.3145
Molecular Formula:C15H23O4P
InChIKey:VFWCXGDEUUNKEQ-ZHACJKMWSA-N
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Compound 3m
Molecular Weight:210.2078
Molecular Formula:C8H19O4P
InChIKey:NNNOPUDYMBHJBR-UHFFFAOYSA-N
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Compound 3n
Molecular Weight:182.1547
Molecular Formula:C6H15O4P
InChIKey:CPHUZBQLLNFATG-UHFFFAOYSA-N
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Compound 3o
Molecular Weight:238.261
Molecular Formula:C10H23O4P
InChIKey:LPEHYIFHDCJDQL-UHFFFAOYSA-N
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Compound 3p
Molecular Weight:210.2078
Molecular Formula:C8H19O4P
InChIKey:QGNCNQNIDOVSQB-UHFFFAOYSA-N
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Compound 3q
Molecular Weight:350.4736
Molecular Formula:C18H39O4P
InChIKey:VYQZCUXHAFEBCW-UHFFFAOYSA-N
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Compound 3r
Molecular Weight:264.2983
Molecular Formula:C12H25O4P
InChIKey:DPOFDTXBQLEKTJ-UHFFFAOYSA-N
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Compound 4a
Molecular Weight:254.2604
Molecular Formula:C10H23O5P
InChIKey:JWLULSNLELDACJ-UHFFFAOYSA-N
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Compound 4c
Molecular Weight:240.2338
Molecular Formula:C9H21O5P
InChIKey:RQLBZQBVPYRSKZ-UHFFFAOYSA-N
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Compound 4d
Molecular Weight:212.1806
Molecular Formula:C7H17O5P
InChIKey:ORCCJOZZIFZOTA-UHFFFAOYSA-N
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Compound 4e
Molecular Weight:254.2604
Molecular Formula:C10H23O5P
InChIKey:RDNLIUBQGXYQBX-UHFFFAOYSA-N
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Compound 4f
Molecular Weight:226.2072
Molecular Formula:C8H19O5P
InChIKey:WICAMCWOLDPYBD-UHFFFAOYSA-N
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Compound 4c′
Molecular Weight:196.1812
Molecular Formula:C7H17O4P
InChIKey:UAXIBJPHBMEGSP-UHFFFAOYSA-N
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Compound 4f′
Molecular Weight:182.1547
Molecular Formula:C6H15O4P
InChIKey:CPHUZBQLLNFATG-UHFFFAOYSA-N
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Compound 4b
Molecular Weight:226.2072
Molecular Formula:C8H19O5P
InChIKey:QWWPAGRLNOBUDD-UHFFFAOYSA-N
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Compound 4d′
Molecular Weight:168.1281
Molecular Formula:C5H13O4P
InChIKey:RWIGWWBLTJLKMK-UHFFFAOYSA-N
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Compound 4e′
Molecular Weight:210.2078
Molecular Formula:C8H19O4P
InChIKey:NNNOPUDYMBHJBR-UHFFFAOYSA-N
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Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2′
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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  1. 1 - 36