Get access

Assembly of {Mn2(salen)2}2+ Dimers by Cyclic V4O124− Clusters: A 3 D Compound with Open-Framework Structure Exhibiting Slow Magnetization Relaxation

Authors

  • Ting-Ting Wang,

    1. Nanjing National Laboratory of Microstructure, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-83314502
    Search for more papers by this author
  • Dr. Song-Song Bao,

    1. Nanjing National Laboratory of Microstructure, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-83314502
    Search for more papers by this author
  • Min Ren,

    1. Nanjing National Laboratory of Microstructure, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-83314502
    Search for more papers by this author
  • Zhong-Sheng Cai,

    1. Nanjing National Laboratory of Microstructure, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-83314502
    Search for more papers by this author
  • Ze-Hua Zheng,

    1. Nanjing National Laboratory of Microstructure, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-83314502
    Search for more papers by this author
  • Zhong-Li Xu,

    1. Nanjing National Laboratory of Microstructure, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-83314502
    Search for more papers by this author
  • Prof. Dr. Li-Min Zheng

    Corresponding author
    1. Nanjing National Laboratory of Microstructure, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-83314502
    • Nanjing National Laboratory of Microstructure, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-83314502

    Search for more papers by this author

Abstract

original image

Sit back and relax: The title compound [Mn6(salen)6(H2O)V4O12](ClO4)2⋅7 H2O is the first example of a 3D coordination polymer with embedded out-of-plane MnIII Schiff base dimers, where the Mn2(salen)22+ dimers are connected by the cyclic V4O124− clusters through covalent bonds. Slow magnetization relaxation is observed at low temperature.

Get access to the full text of this article

Ancillary