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Desulfonylation of Tosyl Amides through Catalytic Photoredox Cleavage of N[BOND]S Bond Under Visible-Light Irradiation

Authors

  • Jun Xuan,

    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
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    • These authors contributed equally.

  • Bin-Jie Li,

    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
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    • These authors contributed equally.

  • Zhu-Jia Feng,

    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
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  • Guo-Dong Sun,

    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
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  • Huan-Huan Ma,

    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
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  • Zhi-Wei Yuan,

    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
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  • Dr. Jia-Rong Chen,

    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
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  • Dr. Liang-Qiu Lu,

    Corresponding author
    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
    • Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn

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  • Prof. Dr. Wen-Jing Xiao

    Corresponding author
    1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn
    • Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (P. R. China), Fax: (+86) 27-67862041 http://chem-xiao.ccnu.edu.cn

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Abstract

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All lit up: A novel and efficient desulfonylation method of tosyl amides has been developed by means of visible-light-promoted reductive cleavage of N[BOND]S bonds. This method has a broad substrate scope, good functional group tolerance, and excellent yields.

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