Article
Coordination Compounds of S-Benzyl-(Ferrocenyl)Ethylidene-Dithiocarbazate with Rare Earth Metals
Article first published online: 1 SEP 2010
DOI: 10.1002/bscb.19931020903
Copyright © 1993 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
0037-9646/asset/cover.gif?v=1&s=dd25fea04a863310402facaf2a5d0022c0b5fdf1 "Bulletin des Sociétés Chimiques Belges")
Additional Information
How to Cite
Gang, Z. and Zhi-Quan, J. (1993), Coordination Compounds of S-Benzyl-(Ferrocenyl)Ethylidene-Dithiocarbazate with Rare Earth Metals. Bull. Soc. Chim. Belges, 102: 575–581. doi: 10.1002/bscb.19931020903
Publication History
- Issue published online: 1 SEP 2010
- Article first published online: 1 SEP 2010
- Manuscript Accepted: 6 OCT 1993
- Manuscript Received: 17 SEP 1993
- Abstract
- References
- Cited By
Abstract
A new ligand. S-benzyl-(ferrocenyl)ethylidenedithiocarbazate FcC(CH3) = NNHCSSCH2C6H5 (Ftsbh) (Fc = η5-C5H5FeC5H4) and its complexes with lanthanide, Ln(Ftsb)3 (Ln = lanthanide) have been prepared and characterized. The data of elemental analyses, IR, UV, NMR, molar conductance. TG and DTA show that the ligand coordinates with Ln(III) in thiol form with a molar ratio of 3:1. The complexes are non-electrolytes in DMF and the C-N bonds in complexes became very strong and much more thermostable than that in the ligand due to forming the chelate rings.